New reactivity and selectivity in rhodium-catalysed hydroacylation

New reactivity and selectivity in rhodium-catalysed hydroacylation

<p>This thesis documents the development of two new rhodium(I)-catalysed methodologies. The first shows the use of 1,4-dicarbonyl systems in hydroacylation for the preparation of synthetically valuable alpha-N-amido ketones. The second method is a dynamic kinetic resolution process for the syn...

Fuld beskrivelse

Bibliografiske detaljer
Hovedforfatter:	Pal, R
Andre forfattere:	Willis, M
Format:	Thesis
Sprog:	English
Udgivet:	2020
Fag:	Metal-catalysis Organic synthesis

Lignende værker

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
af: Poingdestre, SJ
Udgivet: (2012)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
af: Ylioja, P
Udgivet: (2011)

New applications of rhodium-catalysed hydroacylation
af: Iwumene, NUN
Udgivet: (2022)

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
af: Lenden, P
Udgivet: (2011)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
af: Majhail, M
Udgivet: (2016)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
af: Barwick-Silk, J
Udgivet: (2018)

Rhodium-catalysed linear-selective alkyne hydroacylation.
af: Poingdestre, S, et al.
Udgivet: (2012)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
af: Pawley, R
Udgivet: (2012)

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation
af: Moseley, D
Udgivet: (2022)

Ketone synthesis via rhodium-catalyzed traceless chelation-controlled hydroacylation reactions
af: Gao, M
Udgivet: (2018)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
af: Pernik, I
Udgivet: (2014)

Asymmetric rhodium catalysed arylation: from ligand design to application
af: Hell, AML
Udgivet: (2020)

Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
af: Osborne, J, et al.
Udgivet: (2008)

Investigating rhodium-catalysed hydroacylation and carbon-carbon bond activation
af: Coxon, T
Udgivet: (2017)

Studies toward the application and development of rhodium-catalysed hydroacylation reactions
af: Neuhaus, J
Udgivet: (2016)

The understanding and development of rhodium-catalysed asymmetric cross-coupling reactions
af: Van Dijk, L
Udgivet: (2021)

Cp*Rh(III)-catalysed enantioselective C(sp3)–H functionalisation
af: Xu, X
Udgivet: (2024)

Exploiting rhodium-catalysed ynamide hydroacylation as a platform for divergent heterocycle synthesis
af: Straker, R, et al.
Udgivet: (2017)

Palladium-catalysed cyclisations of bromoenynamides in the synthesis and applications of amidodienes
af: Greenaway, R
Udgivet: (2013)

Rhodium-catalysed C(sp2)–C(sp2) bond formation via C–H/C–F activation
af: Tian, Panpan, et al.
Udgivet: (2018)

Palladium-catalysed enolate arylation in the synthesis of isoquinolines
af: Gatland, A, et al.
Udgivet: (2014)

Palladium- and copper-catalysed heterocycle synthesis
af: Ball, C
Udgivet: (2014)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
af: González-Rodríguez, C, et al.
Udgivet: (2010)

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate
af: Lenden, P, et al.
Udgivet: (2011)

Rhodium (I) catalyzed intermolecular hydroacylation.
af: Sapmaz, S, et al.
Udgivet: (2001)

Cyclisation cascades via reactive iminium intermediates
af: Gregory, AW
Udgivet: (2014)

SYNERGISMS BETWEEN METAL AND PHOTOREDOX CATALYSIS: DECONVOLUTING COMPLEX SYSTEMS
af: Alessandra A. G. Fernandes, et al.
Udgivet: (2020-08-01)

Gold film-catalysed benzannulation by Microwave-Assisted, Continuous Flow Organic Synthesis (MACOS)
af: Gjergji Shore, et al.
Udgivet: (2009-07-01)

Special Issue: “Advances in Homogeneous Catalysis”
af: Joaquín García-Álvarez
Udgivet: (2020-03-01)

Novel palladium-catalysed routes to aromatic heterocycles
af: Pilgrim, B, et al.
Udgivet: (2013)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
af: Gonzalez-Rodriguez, C, et al.
Udgivet: (2011)

Palladium-catalysed heterocycle synthesis
af: Sadig, JER
Udgivet: (2012)

Synthesis of mono- and bicyclic azacycles via palladium- and ruthenium-catalysed enynamide cycloisomerisation
af: Walker, P, et al.
Udgivet: (2014)

Transition metal catalysed C-C bond formation via C-H functionalisation
af: Truscott, FR
Udgivet: (2012)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
af: Straker, R, et al.
Udgivet: (2018)

Copper-catalyzed radical trans-selective hydroboration of ynamides with N-heterocyclic carbene boranes
af: Kefeng Wang, et al.
Udgivet: (2022-09-01)

Highly Reactive Cyclic Monoaryl Iodoniums Tuned as Carbene Generators Couple with Nucleophiles under Metal-Free Conditions
af: Haiwen Wang, et al.
Udgivet: (2020-07-01)

Recent advances in metal-catalysed oxidation reactions
af: Aleena Raju, et al.
Udgivet: (2025-01-01)

Bifunctional iminophosphorane superbase catalysed enantioselective intramolecular michael reactions
af: Su, G
Udgivet: (2022)

Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
af: Subrahmanya Ishwar Bhat, et al.
Udgivet: (2025-01-01)