Modulating reactivity in iridium bis(N-heterocyclic carbene) complexes: influence of ring size on E-H bond activation chemistry.
The changes in the steric and electronic properties of N-heterocyclic carbenes (NHCs) as a function of ring size have a profound effect on the reactivity of their late transition metal complexes. Comparison of closely related complexes featuring either a saturated 5- or 6-membered NHC, reveals that...
Päätekijät: | , , , , , , |
---|---|
Aineistotyyppi: | Journal article |
Kieli: | English |
Julkaistu: |
Royal Society of Chemistry
2014
|