New titanium imido synthons: syntheses and supramolecular structures.
Reactions of Ti(NMe(2))(2)Cl(2) with a wide range of primary alkyl and arylamines RNH(2) afforded the corresponding 5-coordinate imido titanium compounds Ti(NR)Cl(2)(NHMe(2))(2) (R = (t)Bu (1), (i)Pr (2), CH(2)Ph (3), Ph (4), 2,6-C(6)H(3)Me(2) (5), 2,6-C(6)H(3)(i)Pr(2) (6), 2,4,6-C(6)H(2)F(3) (7), 2...
Main Authors: | Adams, N, Bigmore, H, Blundell, T, Boyd, C, Dubberley, SR, Sealey, A, Cowley, A, Skinner, M, Mountford, P |
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Format: | Journal article |
Language: | English |
Published: |
2005
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