HPCO - A phosphorus-containing analogue of isocyanic acid
We describe the isolation and spectroscopic characterization of the heavier phosphorus‐containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phas...
| Main Authors: | , , , , |
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| Format: | Journal article |
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Wiley
2017
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| _version_ | 1797062194949521408 |
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| author | Hinz, A Labbow, R Rennick, C Schulz, A Goicoechea, J |
| author_facet | Hinz, A Labbow, R Rennick, C Schulz, A Goicoechea, J |
| author_sort | Hinz, A |
| collection | OXFORD |
| description | We describe the isolation and spectroscopic characterization of the heavier phosphorus‐containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution. |
| first_indexed | 2024-03-06T20:42:02Z |
| format | Journal article |
| id | oxford-uuid:349aa256-9e73-47ef-9692-7dcd80150e5c |
| institution | University of Oxford |
| last_indexed | 2024-03-06T20:42:02Z |
| publishDate | 2017 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:349aa256-9e73-47ef-9692-7dcd80150e5c2022-03-26T13:26:58ZHPCO - A phosphorus-containing analogue of isocyanic acidJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:349aa256-9e73-47ef-9692-7dcd80150e5cSymplectic Elements at OxfordWiley2017Hinz, ALabbow, RRennick, CSchulz, AGoicoechea, JWe describe the isolation and spectroscopic characterization of the heavier phosphorus‐containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution. |
| spellingShingle | Hinz, A Labbow, R Rennick, C Schulz, A Goicoechea, J HPCO - A phosphorus-containing analogue of isocyanic acid |
| title | HPCO - A phosphorus-containing analogue of isocyanic acid |
| title_full | HPCO - A phosphorus-containing analogue of isocyanic acid |
| title_fullStr | HPCO - A phosphorus-containing analogue of isocyanic acid |
| title_full_unstemmed | HPCO - A phosphorus-containing analogue of isocyanic acid |
| title_short | HPCO - A phosphorus-containing analogue of isocyanic acid |
| title_sort | hpco a phosphorus containing analogue of isocyanic acid |
| work_keys_str_mv | AT hinza hpcoaphosphoruscontaininganalogueofisocyanicacid AT labbowr hpcoaphosphoruscontaininganalogueofisocyanicacid AT rennickc hpcoaphosphoruscontaininganalogueofisocyanicacid AT schulza hpcoaphosphoruscontaininganalogueofisocyanicacid AT goicoecheaj hpcoaphosphoruscontaininganalogueofisocyanicacid |