1-Methylindole-3-carboxaldehyde oxime derivatives.
1-Methylindole-3-carboxaldehyde oxime, C10H10N2O, (I), and (E)-5-methoxy-1-methylindole-3-carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two molecules...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2001
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| _version_ | 1797062254706819072 |
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| author | Janes, R Potter, B Naylor, M Ferguson, A Patel, K Stratford, MR Wardman, P Everett, SA |
| author_facet | Janes, R Potter, B Naylor, M Ferguson, A Patel, K Stratford, MR Wardman, P Everett, SA |
| author_sort | Janes, R |
| collection | OXFORD |
| description | 1-Methylindole-3-carboxaldehyde oxime, C10H10N2O, (I), and (E)-5-methoxy-1-methylindole-3-carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two molecules in the asymmetric unit. In contrast, oxime (II) exhibits trans geometry and has four molecules in the asymmetric unit, with the geometry of the 5-methoxy group in one molecule differing from that in the other three. Both crystal structures are maintained by hydrogen bonding with no pi-stacking of the indole moiety present. |
| first_indexed | 2024-03-06T20:42:54Z |
| format | Journal article |
| id | oxford-uuid:34da9771-6c78-464c-8d57-96a5a57a1675 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:42:54Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:34da9771-6c78-464c-8d57-96a5a57a16752022-03-26T13:28:41Z1-Methylindole-3-carboxaldehyde oxime derivatives.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:34da9771-6c78-464c-8d57-96a5a57a1675EnglishSymplectic Elements at Oxford2001Janes, RPotter, BNaylor, MFerguson, APatel, KStratford, MRWardman, PEverett, SA1-Methylindole-3-carboxaldehyde oxime, C10H10N2O, (I), and (E)-5-methoxy-1-methylindole-3-carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two molecules in the asymmetric unit. In contrast, oxime (II) exhibits trans geometry and has four molecules in the asymmetric unit, with the geometry of the 5-methoxy group in one molecule differing from that in the other three. Both crystal structures are maintained by hydrogen bonding with no pi-stacking of the indole moiety present. |
| spellingShingle | Janes, R Potter, B Naylor, M Ferguson, A Patel, K Stratford, MR Wardman, P Everett, SA 1-Methylindole-3-carboxaldehyde oxime derivatives. |
| title | 1-Methylindole-3-carboxaldehyde oxime derivatives. |
| title_full | 1-Methylindole-3-carboxaldehyde oxime derivatives. |
| title_fullStr | 1-Methylindole-3-carboxaldehyde oxime derivatives. |
| title_full_unstemmed | 1-Methylindole-3-carboxaldehyde oxime derivatives. |
| title_short | 1-Methylindole-3-carboxaldehyde oxime derivatives. |
| title_sort | 1 methylindole 3 carboxaldehyde oxime derivatives |
| work_keys_str_mv | AT janesr 1methylindole3carboxaldehydeoximederivatives AT potterb 1methylindole3carboxaldehydeoximederivatives AT naylorm 1methylindole3carboxaldehydeoximederivatives AT fergusona 1methylindole3carboxaldehydeoximederivatives AT patelk 1methylindole3carboxaldehydeoximederivatives AT stratfordmr 1methylindole3carboxaldehydeoximederivatives AT wardmanp 1methylindole3carboxaldehydeoximederivatives AT everettsa 1methylindole3carboxaldehydeoximederivatives |