A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST
The synthesis of a new allosteric 2,2′-bipyridyl bis crown ether ligand (3) that binds the diquat dication is described; chelation of a transition metal at the allosteric bipyridyl site forces the bipyridyl function towards coplanarity, restricting the conformational freedom of the two benzo-15-crow...
| Κύριοι συγγραφείς: | , |
|---|---|
| Μορφή: | Journal article |
| Γλώσσα: | English |
| Έκδοση: |
1988
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| _version_ | 1826266794136961024 |
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| author | Beer, P Rothin, A |
| author_facet | Beer, P Rothin, A |
| author_sort | Beer, P |
| collection | OXFORD |
| description | The synthesis of a new allosteric 2,2′-bipyridyl bis crown ether ligand (3) that binds the diquat dication is described; chelation of a transition metal at the allosteric bipyridyl site forces the bipyridyl function towards coplanarity, restricting the conformational freedom of the two benzo-15-crown-5 moieties in such a way as to disfavour the subsequent binding of diquat. |
| first_indexed | 2024-03-06T20:44:22Z |
| format | Journal article |
| id | oxford-uuid:355c3281-b23a-45a3-b107-57b571a6645a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:44:22Z |
| publishDate | 1988 |
| record_format | dspace |
| spelling | oxford-uuid:355c3281-b23a-45a3-b107-57b571a6645a2022-03-26T13:31:33ZA NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUESTJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:355c3281-b23a-45a3-b107-57b571a6645aEnglishSymplectic Elements at Oxford1988Beer, PRothin, AThe synthesis of a new allosteric 2,2′-bipyridyl bis crown ether ligand (3) that binds the diquat dication is described; chelation of a transition metal at the allosteric bipyridyl site forces the bipyridyl function towards coplanarity, restricting the conformational freedom of the two benzo-15-crown-5 moieties in such a way as to disfavour the subsequent binding of diquat. |
| spellingShingle | Beer, P Rothin, A A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST |
| title | A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST |
| title_full | A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST |
| title_fullStr | A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST |
| title_full_unstemmed | A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST |
| title_short | A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST |
| title_sort | new allosteric bis crown ether ligand that displays negative binding co operativity of the diquat dication by the complexation of a transition metal guest |
| work_keys_str_mv | AT beerp anewallostericbiscrownetherligandthatdisplaysnegativebindingcooperativityofthediquatdicationbythecomplexationofatransitionmetalguest AT rothina anewallostericbiscrownetherligandthatdisplaysnegativebindingcooperativityofthediquatdicationbythecomplexationofatransitionmetalguest AT beerp newallostericbiscrownetherligandthatdisplaysnegativebindingcooperativityofthediquatdicationbythecomplexationofatransitionmetalguest AT rothina newallostericbiscrownetherligandthatdisplaysnegativebindingcooperativityofthediquatdicationbythecomplexationofatransitionmetalguest |