Synthesis and conformational analysis of cyclic analogues of inverse gamma-turns.
Gamma-turn analogues comprising a modified dipeptide constrained in an eleven-membered ring were prepared by alkene metathesis and analysed by NMR and molecular modelling studies. The results reveal that some of the cyclic analogues form inverse gamma-turns and preferentially adopt conformations det...
Main Authors: | , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2008
|