The surface chemistry of Hg-containing superconductors by HREM

The surface chemistry of Hg-containing superconductors has been investigated using high resolution electron Microscopy. It was found that the crystal surface of these materials usually decomposed in air by losing Hg, forming a thin amorphous layer containing Ba and Cu. This amorphous layer can be re...

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Main Authors: Zhou, W, Panagopoulos, C, Lee, E, Hodges, J, Peacock, G, Asab, A, Gameson, I, Edwards, P
Format: Conference item
Published: 1997
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author Zhou, W
Panagopoulos, C
Lee, E
Hodges, J
Peacock, G
Asab, A
Gameson, I
Edwards, P
author_facet Zhou, W
Panagopoulos, C
Lee, E
Hodges, J
Peacock, G
Asab, A
Gameson, I
Edwards, P
author_sort Zhou, W
collection OXFORD
description The surface chemistry of Hg-containing superconductors has been investigated using high resolution electron Microscopy. It was found that the crystal surface of these materials usually decomposed in air by losing Hg, forming a thin amorphous layer containing Ba and Cu. This amorphous layer can be recrystallised into some crystallites of barium cuprate under the electron beam annealing. Such recrystallisation did not take place on the surface of Re-doped Hg-1201. Crystals decomposed heavily when they were ground in solvents. A surface dependence of the low temperature low field magnetic susceptibility of Hg-1201 was also observed.
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spelling oxford-uuid:35f1e15c-a057-4e26-aef5-76b7a9de0e2e2022-03-26T13:34:50ZThe surface chemistry of Hg-containing superconductors by HREMConference itemhttp://purl.org/coar/resource_type/c_5794uuid:35f1e15c-a057-4e26-aef5-76b7a9de0e2eSymplectic Elements at Oxford1997Zhou, WPanagopoulos, CLee, EHodges, JPeacock, GAsab, AGameson, IEdwards, PThe surface chemistry of Hg-containing superconductors has been investigated using high resolution electron Microscopy. It was found that the crystal surface of these materials usually decomposed in air by losing Hg, forming a thin amorphous layer containing Ba and Cu. This amorphous layer can be recrystallised into some crystallites of barium cuprate under the electron beam annealing. Such recrystallisation did not take place on the surface of Re-doped Hg-1201. Crystals decomposed heavily when they were ground in solvents. A surface dependence of the low temperature low field magnetic susceptibility of Hg-1201 was also observed.
spellingShingle Zhou, W
Panagopoulos, C
Lee, E
Hodges, J
Peacock, G
Asab, A
Gameson, I
Edwards, P
The surface chemistry of Hg-containing superconductors by HREM
title The surface chemistry of Hg-containing superconductors by HREM
title_full The surface chemistry of Hg-containing superconductors by HREM
title_fullStr The surface chemistry of Hg-containing superconductors by HREM
title_full_unstemmed The surface chemistry of Hg-containing superconductors by HREM
title_short The surface chemistry of Hg-containing superconductors by HREM
title_sort surface chemistry of hg containing superconductors by hrem
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