Synthesis and Characterization of Free and Coordinated 1,2,3-Tripnictolide Anions
We have investigated the chemical reactivity of heptaatomic anionic clusters of the group 15 elements ([E7]3-/[HE 7]2-, E = P, As) toward the symmetric and asymmetrically substituted alkynes diphenylacetylene and phenylacetylene. The results reported herein, alongside a previous report on the reacti...
Main Authors: | Turbervill, R, Jupp, A, McCullough, P, Ergoecmen, D, Goicoechea, J |
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Format: | Journal article |
Sprog: | English |
Udgivet: |
2013
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Lignende værker
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Synthesis of 1,2,3-tripnictolide anions by reaction of group 15 Zintl ions with acetylene. Isolation of [E3C2H2](-) (E = P, As) and preliminary reactivity studies.
af: Turbervill, R, et al.
Udgivet: (2012) -
An asymmetrically derivatized 1,2,3-triphospholide: synthesis and reactivity of the 4-(2'-pyridyl)-1,2,3-triphospholide anion.
af: Turbervill, R, et al.
Udgivet: (2013) -
The 2-phosphaethynolate anion: a convenient synthesis and [2+2] cycloaddition chemistry.
af: Jupp, A, et al.
Udgivet: (2013) -
From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions.
af: Turbervill, R, et al.
Udgivet: (2014) -
Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion.
af: Turbervill, R, et al.
Udgivet: (2012)