Borane to boryl hydride to borylene dihydride: explicit demonstration of boron-to-metal α-hydride migration in aminoborane activation.
The sequence of fundamental steps implicit in the conversion of a dihydroborane to a metal borylene complex have been elucidated for an [Ir(PMe(3))(3)] system. B-H oxidative addition has been applied for the first time to an aminodihydroborane, H(2)BNR(2), leading to the generation of a rare example...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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