Structural complexity in Prussian blue analogues
We survey the most important kinds of structural complexity in Prussian blue analogues, their implications for materials function, and how they might be controlled through judicious choice of composition. We focus on six particular aspects: octahedral tilts, A-site 'slides', Jahn–Teller di...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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Royal Society of Chemistry
2021
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| _version_ | 1797107928005607424 |
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| author | Cattermull, J Pasta, M Goodwin, A |
| author_facet | Cattermull, J Pasta, M Goodwin, A |
| author_sort | Cattermull, J |
| collection | OXFORD |
| description | We survey the most important kinds of structural complexity in Prussian blue analogues, their implications for materials function, and how they might be controlled through judicious choice of composition. We focus on six particular aspects: octahedral tilts, A-site 'slides', Jahn–Teller distortions, A-site species and occupancy, hexacyanometallate vacancies, and framework hydration. The promising K-ion cathode material KxMn[Fe(CN)6]y serves as a recurrent example that illustrates many of these different types of complexity. Our article concludes with a discussion of how the interplay of various distortion mechanisms might be exploited to optimise the performance of this and other related systems, so as to aid in the design of next-generation PBA materials. |
| first_indexed | 2024-03-07T07:22:08Z |
| format | Journal article |
| id | oxford-uuid:368a3be8-5340-4777-a50b-f53cf443263c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T07:22:08Z |
| publishDate | 2021 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:368a3be8-5340-4777-a50b-f53cf443263c2022-10-24T12:03:03ZStructural complexity in Prussian blue analoguesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:368a3be8-5340-4777-a50b-f53cf443263cEnglishSymplectic ElementsRoyal Society of Chemistry2021Cattermull, JPasta, MGoodwin, AWe survey the most important kinds of structural complexity in Prussian blue analogues, their implications for materials function, and how they might be controlled through judicious choice of composition. We focus on six particular aspects: octahedral tilts, A-site 'slides', Jahn–Teller distortions, A-site species and occupancy, hexacyanometallate vacancies, and framework hydration. The promising K-ion cathode material KxMn[Fe(CN)6]y serves as a recurrent example that illustrates many of these different types of complexity. Our article concludes with a discussion of how the interplay of various distortion mechanisms might be exploited to optimise the performance of this and other related systems, so as to aid in the design of next-generation PBA materials. |
| spellingShingle | Cattermull, J Pasta, M Goodwin, A Structural complexity in Prussian blue analogues |
| title | Structural complexity in Prussian blue analogues |
| title_full | Structural complexity in Prussian blue analogues |
| title_fullStr | Structural complexity in Prussian blue analogues |
| title_full_unstemmed | Structural complexity in Prussian blue analogues |
| title_short | Structural complexity in Prussian blue analogues |
| title_sort | structural complexity in prussian blue analogues |
| work_keys_str_mv | AT cattermullj structuralcomplexityinprussianblueanalogues AT pastam structuralcomplexityinprussianblueanalogues AT goodwina structuralcomplexityinprussianblueanalogues |