1-De-oxy-1-fluoro-l-galactitol.
The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de-oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro-hexane-1,2,3,4,5-penta-ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In t...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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| _version_ | 1797062604437323776 |
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| author | Jenkinson, S Best, D Izumori, K Wilson, F Weymouth-Wilson, A Fleet, G Thompson, A |
| author_facet | Jenkinson, S Best, D Izumori, K Wilson, F Weymouth-Wilson, A Fleet, G Thompson, A |
| author_sort | Jenkinson, S |
| collection | OXFORD |
| description | The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de-oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro-hexane-1,2,3,4,5-penta-ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O-H⋯O and O-H⋯F hydrogen bonds, forming a three-dimensional network with each mol-ecule acting as a donor and acceptor for five hydrogen bonds. |
| first_indexed | 2024-03-06T20:47:54Z |
| format | Journal article |
| id | oxford-uuid:368d4c93-2d7b-41a0-86f9-66e4a7b6ccc7 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:47:54Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:368d4c93-2d7b-41a0-86f9-66e4a7b6ccc72022-03-26T13:38:40Z1-De-oxy-1-fluoro-l-galactitol.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:368d4c93-2d7b-41a0-86f9-66e4a7b6ccc7EnglishSymplectic Elements at Oxford2010Jenkinson, SBest, DIzumori, KWilson, FWeymouth-Wilson, AFleet, GThompson, AThe crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de-oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro-hexane-1,2,3,4,5-penta-ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O-H⋯O and O-H⋯F hydrogen bonds, forming a three-dimensional network with each mol-ecule acting as a donor and acceptor for five hydrogen bonds. |
| spellingShingle | Jenkinson, S Best, D Izumori, K Wilson, F Weymouth-Wilson, A Fleet, G Thompson, A 1-De-oxy-1-fluoro-l-galactitol. |
| title | 1-De-oxy-1-fluoro-l-galactitol. |
| title_full | 1-De-oxy-1-fluoro-l-galactitol. |
| title_fullStr | 1-De-oxy-1-fluoro-l-galactitol. |
| title_full_unstemmed | 1-De-oxy-1-fluoro-l-galactitol. |
| title_short | 1-De-oxy-1-fluoro-l-galactitol. |
| title_sort | 1 de oxy 1 fluoro l galactitol |
| work_keys_str_mv | AT jenkinsons 1deoxy1fluorolgalactitol AT bestd 1deoxy1fluorolgalactitol AT izumorik 1deoxy1fluorolgalactitol AT wilsonf 1deoxy1fluorolgalactitol AT weymouthwilsona 1deoxy1fluorolgalactitol AT fleetg 1deoxy1fluorolgalactitol AT thompsona 1deoxy1fluorolgalactitol |