An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques
Simple theory for the electrochemical study of reversible ion transfer processes at micro- and nano-liquid|liquid interfaces supported on a capillary is presented. Closed-form expressions are obtained for the response in normal pulse and differential double pulse voltammetries, which describe adequa...
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| Format: | Journal article |
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2014
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| _version_ | 1797062772048003072 |
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| author | Molina, A Laborda, E Compton, R |
| author_facet | Molina, A Laborda, E Compton, R |
| author_sort | Molina, A |
| collection | OXFORD |
| description | Simple theory for the electrochemical study of reversible ion transfer processes at micro- and nano-liquid|liquid interfaces supported on a capillary is presented. Closed-form expressions are obtained for the response in normal pulse and differential double pulse voltammetries, which describe adequately the particular behaviour of these systems due to the 'asymmetric' ion diffusion inside and outside the capillary. The use of different potential pulse techniques for the determination of the formal potential and diffusion coefficients of the ion is examined. For this, very simple analytical expressions are presented for the half-wave potential in NPV and the peak potential in DDPV. © 2014 Published by Elsevier B.V. |
| first_indexed | 2024-03-06T20:50:21Z |
| format | Journal article |
| id | oxford-uuid:3756ba8a-a200-4910-b685-f040e5e8d3c3 |
| institution | University of Oxford |
| last_indexed | 2024-03-06T20:50:21Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | oxford-uuid:3756ba8a-a200-4910-b685-f040e5e8d3c32022-03-26T13:43:32ZAn approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniquesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3756ba8a-a200-4910-b685-f040e5e8d3c3Symplectic Elements at Oxford2014Molina, ALaborda, ECompton, RSimple theory for the electrochemical study of reversible ion transfer processes at micro- and nano-liquid|liquid interfaces supported on a capillary is presented. Closed-form expressions are obtained for the response in normal pulse and differential double pulse voltammetries, which describe adequately the particular behaviour of these systems due to the 'asymmetric' ion diffusion inside and outside the capillary. The use of different potential pulse techniques for the determination of the formal potential and diffusion coefficients of the ion is examined. For this, very simple analytical expressions are presented for the half-wave potential in NPV and the peak potential in DDPV. © 2014 Published by Elsevier B.V. |
| spellingShingle | Molina, A Laborda, E Compton, R An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques |
| title | An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques |
| title_full | An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques |
| title_fullStr | An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques |
| title_full_unstemmed | An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques |
| title_short | An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques |
| title_sort | approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid liquid interfaces single and double potential pulse techniques |
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