An efficient metal-templated route to C-functionalised derivatives of [12]aneN(4)
The cyclo cocondensation of triethylenetetramine with arylpyruvaldehydes is templated by iron(III) chloride, to give a [12]aneN4 type diimine complex intermediate which may be reduced and demetallated in situ with sodium borohydride giving the saturated [12]aneN4 metal-free macrocycle in up to 60% o...
Main Authors: | , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
1996
|
Summary: | The cyclo cocondensation of triethylenetetramine with arylpyruvaldehydes is templated by iron(III) chloride, to give a [12]aneN4 type diimine complex intermediate which may be reduced and demetallated in situ with sodium borohydride giving the saturated [12]aneN4 metal-free macrocycle in up to 60% overall yields; photophysical studies are used to demonstrate the similarity between the aryl functionalised [12]aneN4 derivatives formed by this route and analogues derived from [12]aneN4 itself. |
---|