Dynamic intermediates in the radical cation diels–alder cycloaddition: lifetime and suprafacial stereoselectivity

Dynamic intermediates in the radical cation diels–alder cycloaddition: lifetime and suprafacial stereoselectivity

Cation radical Diels–Alder cycloadditions proceed via an acyclic intermediate that exists on a flat region of the potential energy surface. Competition between cyclization and C–C bond rotation results in varying levels of suprafacial stereoselectivity. Quasi-classical trajectories were used to expl...

Πλήρης περιγραφή

Λεπτομέρειες βιβλιογραφικής εγγραφής
Κύριοι συγγραφείς:	Tan, J, Hirvonen, V, Paton, R
Μορφή:	Journal article
Γλώσσα:	English
Έκδοση:	American Chemical Society 2018

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