Corroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopy

A collection of Hellenistic–Roman glyptics, kept at the Regional Archaeological Museum “Paolo Orsi” (Syracuse, Italy), was investigated in situ with portable Raman spectroscopy with the aim of assessing the viability of this approach, not only for the immediate identification of the gemstones but al...

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Main Authors: Caggiani, MC, Cavarra, M, Barone, G, Coccato, A, Manenti, AM, Mazzoleni, P
Format: Journal article
Language:English
Published: Wiley 2023
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author Caggiani, MC
Cavarra, M
Barone, G
Coccato, A
Manenti, AM
Mazzoleni, P
author_facet Caggiani, MC
Cavarra, M
Barone, G
Coccato, A
Manenti, AM
Mazzoleni, P
author_sort Caggiani, MC
collection OXFORD
description A collection of Hellenistic–Roman glyptics, kept at the Regional Archaeological Museum “Paolo Orsi” (Syracuse, Italy), was investigated in situ with portable Raman spectroscopy with the aim of assessing the viability of this approach, not only for the immediate identification of the gemstones but also for a more in-depth successive data treatment. At the same time, a corroboration of the autoptic identification of the materials, both archeological and belonging to historical collections, was looked for in order to verify and potentially correct what reported in the museum catalogue. Actually, most of the identifications could be confirmed, the glyptics being mainly made of chalcedony. Other materials found were garnet, glass, and amber. The larger group of chalcedony Raman spectra was subjected to principal components analysis treatment that, after appropriate pretreatment, resulted successful in separating spectra with higher or lower contribution of the band due to the presence of moganite and Si OH bonds. The garnet spectra were instead subjected to quantitative study to identify the main end member. Both the quick identifications and the more detailed studies on chalcedonies and garnets were achieved thanks to the nondestructive and noninvasive investigation, directly in situ, with no sample preparation and minimal interference with the museum's activities.
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spelling oxford-uuid:37f9c091-4e72-475f-99d4-54a4f7694e762024-02-29T10:11:21ZCorroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopyJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:37f9c091-4e72-475f-99d4-54a4f7694e76EnglishSymplectic ElementsWiley2023Caggiani, MCCavarra, MBarone, GCoccato, AManenti, AMMazzoleni, PA collection of Hellenistic–Roman glyptics, kept at the Regional Archaeological Museum “Paolo Orsi” (Syracuse, Italy), was investigated in situ with portable Raman spectroscopy with the aim of assessing the viability of this approach, not only for the immediate identification of the gemstones but also for a more in-depth successive data treatment. At the same time, a corroboration of the autoptic identification of the materials, both archeological and belonging to historical collections, was looked for in order to verify and potentially correct what reported in the museum catalogue. Actually, most of the identifications could be confirmed, the glyptics being mainly made of chalcedony. Other materials found were garnet, glass, and amber. The larger group of chalcedony Raman spectra was subjected to principal components analysis treatment that, after appropriate pretreatment, resulted successful in separating spectra with higher or lower contribution of the band due to the presence of moganite and Si OH bonds. The garnet spectra were instead subjected to quantitative study to identify the main end member. Both the quick identifications and the more detailed studies on chalcedonies and garnets were achieved thanks to the nondestructive and noninvasive investigation, directly in situ, with no sample preparation and minimal interference with the museum's activities.
spellingShingle Caggiani, MC
Cavarra, M
Barone, G
Coccato, A
Manenti, AM
Mazzoleni, P
Corroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopy
title Corroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopy
title_full Corroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopy
title_fullStr Corroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopy
title_full_unstemmed Corroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopy
title_short Corroborating the autoptic identification of archeological glyptics in museum collections: the contribution of portable Raman spectroscopy
title_sort corroborating the autoptic identification of archeological glyptics in museum collections the contribution of portable raman spectroscopy
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