High-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperature
Although carbon black nanoparticles (CBs) at ca. 10 wt.% are widely used as a conductive additives for energy storage electrodes for lithium ion batteries and supercapacitors, they are not extensively used as the active materials for such devices due to their poor ionic conductivity and wettability....
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Journal article |
| Published: |
Elsevier
2017
|
| _version_ | 1826267331078127616 |
|---|---|
| author | Phattharasupakun, N Wutthiprom, J Suktha, P Iamprasertkun, P Chanlek, N Shepherd, C Hadzifejzovic, E Moloney, M Foord, J Sawangphruk, M |
| author_facet | Phattharasupakun, N Wutthiprom, J Suktha, P Iamprasertkun, P Chanlek, N Shepherd, C Hadzifejzovic, E Moloney, M Foord, J Sawangphruk, M |
| author_sort | Phattharasupakun, N |
| collection | OXFORD |
| description | Although carbon black nanoparticles (CBs) at ca. 10 wt.% are widely used as a conductive additives for energy storage electrodes for lithium ion batteries and supercapacitors, they are not extensively used as the active materials for such devices due to their poor ionic conductivity and wettability. In this work, CBs were oxidized by a process of refluxing with conc. HNO3 for 6-72 h, providing oxidized CBs (OCBs) with different oxygen-containing groups (i.e., carboxyl, hydroxyl, and carbonyl) and contents. The OCBs refluxed for 12 h have ca. 2.0-fold higher accessible active surface area than that of the pristine CBs. The as-fabricated symmetric supercapacitor using OCBs refluxed for 12 h with a [BMP][DCA] ionic liquid electrolyte exhibits specific energy and maximum specific power of 88 Wh kg-1 and 8429 W kg-1, respectively with the capacitance retention over 97% after 6000 cycles. A single coin-cell supercapacitor prototype fully charged can supply electrical power to a red LED over 24 min. This device may be practically used as a battery replacement in high power applications. |
| first_indexed | 2024-03-06T20:52:32Z |
| format | Journal article |
| id | oxford-uuid:381733d6-dab1-4906-91af-ae8905bd418f |
| institution | University of Oxford |
| last_indexed | 2024-03-06T20:52:32Z |
| publishDate | 2017 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:381733d6-dab1-4906-91af-ae8905bd418f2022-03-26T13:47:53ZHigh-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperatureJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:381733d6-dab1-4906-91af-ae8905bd418fSymplectic Elements at OxfordElsevier2017Phattharasupakun, NWutthiprom, JSuktha, PIamprasertkun, PChanlek, NShepherd, CHadzifejzovic, EMoloney, MFoord, JSawangphruk, MAlthough carbon black nanoparticles (CBs) at ca. 10 wt.% are widely used as a conductive additives for energy storage electrodes for lithium ion batteries and supercapacitors, they are not extensively used as the active materials for such devices due to their poor ionic conductivity and wettability. In this work, CBs were oxidized by a process of refluxing with conc. HNO3 for 6-72 h, providing oxidized CBs (OCBs) with different oxygen-containing groups (i.e., carboxyl, hydroxyl, and carbonyl) and contents. The OCBs refluxed for 12 h have ca. 2.0-fold higher accessible active surface area than that of the pristine CBs. The as-fabricated symmetric supercapacitor using OCBs refluxed for 12 h with a [BMP][DCA] ionic liquid electrolyte exhibits specific energy and maximum specific power of 88 Wh kg-1 and 8429 W kg-1, respectively with the capacitance retention over 97% after 6000 cycles. A single coin-cell supercapacitor prototype fully charged can supply electrical power to a red LED over 24 min. This device may be practically used as a battery replacement in high power applications. |
| spellingShingle | Phattharasupakun, N Wutthiprom, J Suktha, P Iamprasertkun, P Chanlek, N Shepherd, C Hadzifejzovic, E Moloney, M Foord, J Sawangphruk, M High-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperature |
| title | High-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperature |
| title_full | High-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperature |
| title_fullStr | High-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperature |
| title_full_unstemmed | High-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperature |
| title_short | High-performance supercapacitors of carboxylate-modified hollow carbon nanospheres coated on flexible carbon fibre paper: Effects of oxygen-containing group contents, electrolytes and operating temperature |
| title_sort | high performance supercapacitors of carboxylate modified hollow carbon nanospheres coated on flexible carbon fibre paper effects of oxygen containing group contents electrolytes and operating temperature |
| work_keys_str_mv | AT phattharasupakunn highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT wutthipromj highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT sukthap highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT iamprasertkunp highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT chanlekn highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT shepherdc highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT hadzifejzovice highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT moloneym highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT foordj highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature AT sawangphrukm highperformancesupercapacitorsofcarboxylatemodifiedhollowcarbonnanospherescoatedonflexiblecarbonfibrepapereffectsofoxygencontaininggroupcontentselectrolytesandoperatingtemperature |