Self-assembly in the electrical double layer of ionic liquids.
We have studied the structure of two ionic liquids confined between negatively charged mica sheets. Both liquids exhibit interfacial layering, however the repeat distance is dramatically different for the two liquids. Our results suggest a transition from alternating cation-anion monolayers to tail-...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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| _version_ | 1797063010470068224 |
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| author | Perkin, S Crowhurst, L Niedermeyer, H Welton, T Smith, A Gosvami, N |
| author_facet | Perkin, S Crowhurst, L Niedermeyer, H Welton, T Smith, A Gosvami, N |
| author_sort | Perkin, S |
| collection | OXFORD |
| description | We have studied the structure of two ionic liquids confined between negatively charged mica sheets. Both liquids exhibit interfacial layering, however the repeat distance is dramatically different for the two liquids. Our results suggest a transition from alternating cation-anion monolayers to tail-to-tail cation bilayers when the length of the cation hydrocarbon chain is increased. |
| first_indexed | 2024-03-06T20:53:44Z |
| format | Journal article |
| id | oxford-uuid:387a2a14-3d00-495b-a0d7-e0715e43ef46 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:53:44Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:387a2a14-3d00-495b-a0d7-e0715e43ef462022-03-26T13:50:17ZSelf-assembly in the electrical double layer of ionic liquids.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:387a2a14-3d00-495b-a0d7-e0715e43ef46EnglishSymplectic Elements at Oxford2011Perkin, SCrowhurst, LNiedermeyer, HWelton, TSmith, AGosvami, NWe have studied the structure of two ionic liquids confined between negatively charged mica sheets. Both liquids exhibit interfacial layering, however the repeat distance is dramatically different for the two liquids. Our results suggest a transition from alternating cation-anion monolayers to tail-to-tail cation bilayers when the length of the cation hydrocarbon chain is increased. |
| spellingShingle | Perkin, S Crowhurst, L Niedermeyer, H Welton, T Smith, A Gosvami, N Self-assembly in the electrical double layer of ionic liquids. |
| title | Self-assembly in the electrical double layer of ionic liquids. |
| title_full | Self-assembly in the electrical double layer of ionic liquids. |
| title_fullStr | Self-assembly in the electrical double layer of ionic liquids. |
| title_full_unstemmed | Self-assembly in the electrical double layer of ionic liquids. |
| title_short | Self-assembly in the electrical double layer of ionic liquids. |
| title_sort | self assembly in the electrical double layer of ionic liquids |
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