Structural and photophysical properties of coordination networks combining [Ru(bipy)(CN)4]2- anions and lanthanide(III) cations: rates of photoinduced Ru-to-lanthanide energy transfer and sensitized near-infrared luminescence.

Co-crystallization of K2[Ru(bipy)(CN)4] with lanthanide(III) salts (Ln = Pr, Nd, Gd, Er, Yb) from aqueous solution affords coordination oligomers and networks in which the [Ru(bipy)(CN)4]2- unit is connected to the lanthanide cation via Ru-CN-Ln bridges. The complexes fall into two structural types:...

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প্রধান লেখক: Davies, G, Pope, S, Adams, H, Faulkner, S, Ward, MD
বিন্যাস: Journal article
ভাষা:English
প্রকাশিত: 2005