Structural and photophysical properties of coordination networks combining [Ru(bipy)(CN)4]2- anions and lanthanide(III) cations: rates of photoinduced Ru-to-lanthanide energy transfer and sensitized near-infrared luminescence.

Co-crystallization of K2[Ru(bipy)(CN)4] with lanthanide(III) salts (Ln = Pr, Nd, Gd, Er, Yb) from aqueous solution affords coordination oligomers and networks in which the [Ru(bipy)(CN)4]2- unit is connected to the lanthanide cation via Ru-CN-Ln bridges. The complexes fall into two structural types:...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron: Davies, G, Pope, S, Adams, H, Faulkner, S, Ward, MD
Fformat: Journal article
Iaith:English
Cyhoeddwyd: 2005