NEW STRATEGY FOR THE SYNTHESIS OF THE TAXANE DITERPENES - FORMATION OF THE 8-MEMBERED B-RING OF TAXOL BY SEMI-PINACOL REARRANGEMENT

Eitemau Tebyg

• Taxane diterpenes .3. Formation of the eight-membered B-ring by semi-pinacol rearrangement
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• NEW STRATEGY FOR THE SYNTHESIS OF THE TAXANE DITERPENES - FORMATION OF THE BC-RINGS OF TAXOL VIA A [5+2]-PYRYLIUM YLIDE-ALKENE CYCLIZATION, RING EXPANSION STRATEGY
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• Taxane diterpenes .2. Synthesis of the 7-deoxy ABC taxane skeleton, and reactions of the A-ring
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• Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors.
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• Brönsted Acid of Keggin Type Polyoxometalate Catalyzed Pinacol Rearrangement
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  Cyhoeddwyd: (2014-08-01)