Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K () and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J'/J| = 3.3 × 10-3, demonstr...

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Main Authors: Huddart, B, Brambleby, J, Lancaster, T, Goddard, P, Xiao, F, Blundell, S, Pratt, F, Singleton, J, Macchi, P, Scatena, R, Barton, A, Manson, J
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2018
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author Huddart, B
Brambleby, J
Lancaster, T
Goddard, P
Xiao, F
Blundell, S
Pratt, F
Singleton, J
Macchi, P
Scatena, R
Barton, A
Manson, J
author_facet Huddart, B
Brambleby, J
Lancaster, T
Goddard, P
Xiao, F
Blundell, S
Pratt, F
Singleton, J
Macchi, P
Scatena, R
Barton, A
Manson, J
author_sort Huddart, B
collection OXFORD
description The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K () and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J'/J| = 3.3 × 10-3, demonstrating a high degree of isolation for the Cu chains.
first_indexed 2024-03-06T20:56:18Z
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spelling oxford-uuid:39621b20-3ac5-4d33-9d37-43d1ebae5df02022-03-26T13:55:11ZMagnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:39621b20-3ac5-4d33-9d37-43d1ebae5df0EnglishSymplectic Elements at OxfordRoyal Society of Chemistry2018Huddart, BBrambleby, JLancaster, TGoddard, PXiao, FBlundell, SPratt, FSingleton, JMacchi, PScatena, RBarton, AManson, JThe quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K () and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J'/J| = 3.3 × 10-3, demonstrating a high degree of isolation for the Cu chains.
spellingShingle Huddart, B
Brambleby, J
Lancaster, T
Goddard, P
Xiao, F
Blundell, S
Pratt, F
Singleton, J
Macchi, P
Scatena, R
Barton, A
Manson, J
Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
title Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
title_full Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
title_fullStr Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
title_full_unstemmed Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
title_short Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
title_sort magnetic order and enhanced exchange in the quasi one dimensional molecule based antiferromagnet cu no3 2 pyz 3
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