INFRARED PREDISSOCIATION SPECTRUM OF HENE+
One hundred and seven transitions of the HeNe+ ion have been observed using the technique of infrared predissociation spectroscopy. Seventy-eight of the lines have been assigned to rotational components of the A22Π 1 2 -X2Σ+ system. Our analysis leads to a modification of the assignment of the B2Σ+...
Main Authors: | , |
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Format: | Journal article |
Language: | English |
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1985
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author | Carrington, A Softley, T |
author_facet | Carrington, A Softley, T |
author_sort | Carrington, A |
collection | OXFORD |
description | One hundred and seven transitions of the HeNe+ ion have been observed using the technique of infrared predissociation spectroscopy. Seventy-eight of the lines have been assigned to rotational components of the A22Π 1 2 -X2Σ+ system. Our analysis leads to a modification of the assignment of the B2Σ+ -X2Σ+ bands of the optical emission spectrum. The predissociation mechanism is unusual in that there are no potential curve crossings between the predissociating state and the perturbing states. Predissociation lifetimes have been calculated for the individual levels and are compared with those obtained from the obserbed spectroscope linewidths. © 1985. |
first_indexed | 2024-03-06T20:57:37Z |
format | Journal article |
id | oxford-uuid:39cbb91b-fbff-455b-9b5f-b02554f62b7d |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T20:57:37Z |
publishDate | 1985 |
record_format | dspace |
spelling | oxford-uuid:39cbb91b-fbff-455b-9b5f-b02554f62b7d2022-03-26T13:57:40ZINFRARED PREDISSOCIATION SPECTRUM OF HENE+Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:39cbb91b-fbff-455b-9b5f-b02554f62b7dEnglishSymplectic Elements at Oxford1985Carrington, ASoftley, TOne hundred and seven transitions of the HeNe+ ion have been observed using the technique of infrared predissociation spectroscopy. Seventy-eight of the lines have been assigned to rotational components of the A22Π 1 2 -X2Σ+ system. Our analysis leads to a modification of the assignment of the B2Σ+ -X2Σ+ bands of the optical emission spectrum. The predissociation mechanism is unusual in that there are no potential curve crossings between the predissociating state and the perturbing states. Predissociation lifetimes have been calculated for the individual levels and are compared with those obtained from the obserbed spectroscope linewidths. © 1985. |
spellingShingle | Carrington, A Softley, T INFRARED PREDISSOCIATION SPECTRUM OF HENE+ |
title | INFRARED PREDISSOCIATION SPECTRUM OF HENE+ |
title_full | INFRARED PREDISSOCIATION SPECTRUM OF HENE+ |
title_fullStr | INFRARED PREDISSOCIATION SPECTRUM OF HENE+ |
title_full_unstemmed | INFRARED PREDISSOCIATION SPECTRUM OF HENE+ |
title_short | INFRARED PREDISSOCIATION SPECTRUM OF HENE+ |
title_sort | infrared predissociation spectrum of hene |
work_keys_str_mv | AT carringtona infraredpredissociationspectrumofhene AT softleyt infraredpredissociationspectrumofhene |