Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides
Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products a...
| প্রধান লেখক: | |
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| বিন্যাস: | Journal article |
| প্রকাশিত: |
American Chemical Society
2019
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| _version_ | 1826267749603606528 |
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| author | Fletcher, S |
| author_facet | Fletcher, S |
| author_sort | Fletcher, S |
| collection | OXFORD |
| description | Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products and is compatible with heterocyclic allyl chloride electrophiles. |
| first_indexed | 2024-03-06T20:58:58Z |
| format | Journal article |
| id | oxford-uuid:3a3b52e4-3b64-4419-b86a-a597a2313d98 |
| institution | University of Oxford |
| last_indexed | 2024-03-06T20:58:58Z |
| publishDate | 2019 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:3a3b52e4-3b64-4419-b86a-a597a2313d982022-03-26T14:00:21ZHighly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chloridesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3a3b52e4-3b64-4419-b86a-a597a2313d98Symplectic Elements at OxfordAmerican Chemical Society2019Fletcher, SHighly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products and is compatible with heterocyclic allyl chloride electrophiles. |
| spellingShingle | Fletcher, S Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides |
| title | Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides |
| title_full | Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides |
| title_fullStr | Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides |
| title_full_unstemmed | Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides |
| title_short | Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides |
| title_sort | highly enantioselective hiyama cross coupling via rh catalyzed allylic arylation of racemic allyl chlorides |
| work_keys_str_mv | AT fletchers highlyenantioselectivehiyamacrosscouplingviarhcatalyzedallylicarylationofracemicallylchlorides |