Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides

Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products a...

وصف كامل

التفاصيل البيبلوغرافية
المؤلف الرئيسي: Fletcher, S
التنسيق: Journal article
منشور في: American Chemical Society 2019