Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides

Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products a...

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Tác giả chính: Fletcher, S
Định dạng: Journal article
Được phát hành: American Chemical Society 2019