Can heterometallic 1-dimensional chains support current rectification?
To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectifica...
| Main Authors: | , , |
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| פורמט: | Journal article |
| שפה: | English |
| יצא לאור: |
2013
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| _version_ | 1826267817264021504 |
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| author | DeBrincat, D Keers, O McGrady, J |
| author_facet | DeBrincat, D Keers, O McGrady, J |
| author_sort | DeBrincat, D |
| collection | OXFORD |
| description | To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios. |
| first_indexed | 2024-03-06T21:00:02Z |
| format | Journal article |
| id | oxford-uuid:3a93b2c1-ac18-4da9-a7ed-9adf8479c75f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:00:02Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:3a93b2c1-ac18-4da9-a7ed-9adf8479c75f2022-03-26T14:02:25ZCan heterometallic 1-dimensional chains support current rectification?Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3a93b2c1-ac18-4da9-a7ed-9adf8479c75fEnglishSymplectic Elements at Oxford2013DeBrincat, DKeers, OMcGrady, JTo what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios. |
| spellingShingle | DeBrincat, D Keers, O McGrady, J Can heterometallic 1-dimensional chains support current rectification? |
| title | Can heterometallic 1-dimensional chains support current rectification? |
| title_full | Can heterometallic 1-dimensional chains support current rectification? |
| title_fullStr | Can heterometallic 1-dimensional chains support current rectification? |
| title_full_unstemmed | Can heterometallic 1-dimensional chains support current rectification? |
| title_short | Can heterometallic 1-dimensional chains support current rectification? |
| title_sort | can heterometallic 1 dimensional chains support current rectification |
| work_keys_str_mv | AT debrincatd canheterometallic1dimensionalchainssupportcurrentrectification AT keerso canheterometallic1dimensionalchainssupportcurrentrectification AT mcgradyj canheterometallic1dimensionalchainssupportcurrentrectification |