Can heterometallic 1-dimensional chains support current rectification?

To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectifica...

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Detalles Bibliográficos
Main Authors: DeBrincat, D, Keers, O, McGrady, J
Formato: Journal article
Idioma:English
Publicado: 2013