Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.

Oxidation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide in the presence of Cl3CCO2H proceeds with high levels of anti-diastereoselectivity (97% de), with no competing side reactions, allowing access to 1,2-anti-2,3-anti-3-aminocyclohexane-1,2-diol after deprotection.

Bibliografiset tiedot
Päätekijät: Aciro, C, Davies, S, Kurosawa, W, Roberts, P, Russell, A, Thomson, J
Aineistotyyppi: Journal article
Kieli:English
Julkaistu: 2009
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author Aciro, C
Davies, S
Kurosawa, W
Roberts, P
Russell, A
Thomson, J
author_facet Aciro, C
Davies, S
Kurosawa, W
Roberts, P
Russell, A
Thomson, J
author_sort Aciro, C
collection OXFORD
description Oxidation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide in the presence of Cl3CCO2H proceeds with high levels of anti-diastereoselectivity (97% de), with no competing side reactions, allowing access to 1,2-anti-2,3-anti-3-aminocyclohexane-1,2-diol after deprotection.
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spelling oxford-uuid:3b0afd92-19cb-40db-8c4a-1081a2648c982022-03-26T14:05:15ZHighly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3b0afd92-19cb-40db-8c4a-1081a2648c98EnglishSymplectic Elements at Oxford2009Aciro, CDavies, SKurosawa, WRoberts, PRussell, AThomson, JOxidation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide in the presence of Cl3CCO2H proceeds with high levels of anti-diastereoselectivity (97% de), with no competing side reactions, allowing access to 1,2-anti-2,3-anti-3-aminocyclohexane-1,2-diol after deprotection.
spellingShingle Aciro, C
Davies, S
Kurosawa, W
Roberts, P
Russell, A
Thomson, J
Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.
title Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.
title_full Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.
title_fullStr Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.
title_full_unstemmed Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.
title_short Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.
title_sort highly diastereoselective anti dihydroxylation of 3 n n dibenzylaminocyclohex 1 ene n oxide
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AT kurosawaw highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide
AT robertsp highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide
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