Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.
Oxidation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide in the presence of Cl3CCO2H proceeds with high levels of anti-diastereoselectivity (97% de), with no competing side reactions, allowing access to 1,2-anti-2,3-anti-3-aminocyclohexane-1,2-diol after deprotection.
| Egile Nagusiak: | , , , , , |
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| Formatua: | Journal article |
| Hizkuntza: | English |
| Argitaratua: |
2009
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| _version_ | 1826267912651931648 |
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| author | Aciro, C Davies, S Kurosawa, W Roberts, P Russell, A Thomson, J |
| author_facet | Aciro, C Davies, S Kurosawa, W Roberts, P Russell, A Thomson, J |
| author_sort | Aciro, C |
| collection | OXFORD |
| description | Oxidation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide in the presence of Cl3CCO2H proceeds with high levels of anti-diastereoselectivity (97% de), with no competing side reactions, allowing access to 1,2-anti-2,3-anti-3-aminocyclohexane-1,2-diol after deprotection. |
| first_indexed | 2024-03-06T21:01:32Z |
| format | Journal article |
| id | oxford-uuid:3b0afd92-19cb-40db-8c4a-1081a2648c98 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:01:32Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:3b0afd92-19cb-40db-8c4a-1081a2648c982022-03-26T14:05:15ZHighly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3b0afd92-19cb-40db-8c4a-1081a2648c98EnglishSymplectic Elements at Oxford2009Aciro, CDavies, SKurosawa, WRoberts, PRussell, AThomson, JOxidation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide in the presence of Cl3CCO2H proceeds with high levels of anti-diastereoselectivity (97% de), with no competing side reactions, allowing access to 1,2-anti-2,3-anti-3-aminocyclohexane-1,2-diol after deprotection. |
| spellingShingle | Aciro, C Davies, S Kurosawa, W Roberts, P Russell, A Thomson, J Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide. |
| title | Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide. |
| title_full | Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide. |
| title_fullStr | Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide. |
| title_full_unstemmed | Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide. |
| title_short | Highly diastereoselective anti-dihydroxylation of 3-N,N-dibenzylaminocyclohex-1-ene N-oxide. |
| title_sort | highly diastereoselective anti dihydroxylation of 3 n n dibenzylaminocyclohex 1 ene n oxide |
| work_keys_str_mv | AT aciroc highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide AT daviess highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide AT kurosawaw highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide AT robertsp highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide AT russella highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide AT thomsonj highlydiastereoselectiveantidihydroxylationof3nndibenzylaminocyclohex1enenoxide |