A radical intermediate in tyrosine scission to the CO and CN⁻ ligands of FeFe hydrogenase

A radical intermediate in tyrosine scission to the CO and CN⁻ ligands of FeFe hydrogenase

The radical <em>S</em>-adenosylmethionine (SAM) enzyme HydG lyses free L-tyrosine to produce CO and CN<em><sup>−</sup></em> for the assembly of the catalytic H cluster of FeFe hydrogenase. We used electron paramagnetic resonance spectroscopy to detect and characte...

Podrobná bibliografie
Hlavní autoři:	Kuchenreuther, J, Myers, W, Stich, T, George, S, NejatyJahromy, Y, Swartz, JR, Britt, R
Médium:	Journal article
Jazyk:	English
Vydáno:	American Association for the Advancement of Science 2013

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