A radical intermediate in tyrosine scission to the CO and CN⁻ ligands of FeFe hydrogenase
The radical <em>S</em>-adenosylmethionine (SAM) enzyme HydG lyses free L-tyrosine to produce CO and CN<em><sup>−</sup></em> for the assembly of the catalytic H cluster of FeFe hydrogenase. We used electron paramagnetic resonance spectroscopy to detect and characte...
| Main Authors: | , , , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
American Association for the Advancement of Science
2013
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