Structures of platinum oxide clusters in the gas phase.
The structures of small gas-phase Pt(n)O(2m)(+) (n = 1-6, m = 1, 2) cluster cations have been investigated in a combined infrared multiple photon dissociation (IRMPD) spectroscopy and density functional theory (DFT) study. On the basis of the infrared spectra obtained, it is concluded that in most c...
| Hauptverfasser: | , , , , , |
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| Format: | Journal article |
| Sprache: | English |
| Veröffentlicht: |
2013
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| _version_ | 1826268197602459648 |
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| author | Kerpal, C Harding, D Hermes, A Meijer, G Mackenzie, S Fielicke, A |
| author_facet | Kerpal, C Harding, D Hermes, A Meijer, G Mackenzie, S Fielicke, A |
| author_sort | Kerpal, C |
| collection | OXFORD |
| description | The structures of small gas-phase Pt(n)O(2m)(+) (n = 1-6, m = 1, 2) cluster cations have been investigated in a combined infrared multiple photon dissociation (IRMPD) spectroscopy and density functional theory (DFT) study. On the basis of the infrared spectra obtained, it is concluded that in most clusters oxygen is bound dissociatively, preferring 2-fold bridge binding motifs, sometimes combined with singly coordinated terminal binding. Comparison of the oxide cluster structures with those of bare cationic platinum clusters reported previously reveals major structural changes induced in the platinum core upon oxygen binding. For some cluster sizes the presence of the Ar messenger atom(s) is found to induce a significant change in the observed cluster structure. |
| first_indexed | 2024-03-06T21:05:58Z |
| format | Journal article |
| id | oxford-uuid:3c768200-ead0-4839-b541-183dbd028469 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:05:58Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:3c768200-ead0-4839-b541-183dbd0284692022-03-26T14:13:45ZStructures of platinum oxide clusters in the gas phase.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3c768200-ead0-4839-b541-183dbd028469EnglishSymplectic Elements at Oxford2013Kerpal, CHarding, DHermes, AMeijer, GMackenzie, SFielicke, AThe structures of small gas-phase Pt(n)O(2m)(+) (n = 1-6, m = 1, 2) cluster cations have been investigated in a combined infrared multiple photon dissociation (IRMPD) spectroscopy and density functional theory (DFT) study. On the basis of the infrared spectra obtained, it is concluded that in most clusters oxygen is bound dissociatively, preferring 2-fold bridge binding motifs, sometimes combined with singly coordinated terminal binding. Comparison of the oxide cluster structures with those of bare cationic platinum clusters reported previously reveals major structural changes induced in the platinum core upon oxygen binding. For some cluster sizes the presence of the Ar messenger atom(s) is found to induce a significant change in the observed cluster structure. |
| spellingShingle | Kerpal, C Harding, D Hermes, A Meijer, G Mackenzie, S Fielicke, A Structures of platinum oxide clusters in the gas phase. |
| title | Structures of platinum oxide clusters in the gas phase. |
| title_full | Structures of platinum oxide clusters in the gas phase. |
| title_fullStr | Structures of platinum oxide clusters in the gas phase. |
| title_full_unstemmed | Structures of platinum oxide clusters in the gas phase. |
| title_short | Structures of platinum oxide clusters in the gas phase. |
| title_sort | structures of platinum oxide clusters in the gas phase |
| work_keys_str_mv | AT kerpalc structuresofplatinumoxideclustersinthegasphase AT hardingd structuresofplatinumoxideclustersinthegasphase AT hermesa structuresofplatinumoxideclustersinthegasphase AT meijerg structuresofplatinumoxideclustersinthegasphase AT mackenzies structuresofplatinumoxideclustersinthegasphase AT fielickea structuresofplatinumoxideclustersinthegasphase |