SPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEP
An explanation of some unexpected enchancements in the chemically induced dynamic electron polarization (CIDEP) spectra of ketyl radicals is suggested. It requires an electron exchange interaction that is negative for proximate radicals but positive for more distant ones and that geminate radical pa...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1984
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| _version_ | 1797064003083567104 |
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| author | Grant, A Green, N Hore, P Mclauchlan, K |
| author_facet | Grant, A Green, N Hore, P Mclauchlan, K |
| author_sort | Grant, A |
| collection | OXFORD |
| description | An explanation of some unexpected enchancements in the chemically induced dynamic electron polarization (CIDEP) spectra of ketyl radicals is suggested. It requires an electron exchange interaction that is negative for proximate radicals but positive for more distant ones and that geminate radical pairs are formed at a separation smaller than that at which random encounter pairs of the same radicals are able to react. © 1984. |
| first_indexed | 2024-03-06T21:08:04Z |
| format | Journal article |
| id | oxford-uuid:3d2763e4-b965-4ebc-b188-c625fe2afac8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:08:04Z |
| publishDate | 1984 |
| record_format | dspace |
| spelling | oxford-uuid:3d2763e4-b965-4ebc-b188-c625fe2afac82022-03-26T14:17:52ZSPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEPJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3d2763e4-b965-4ebc-b188-c625fe2afac8EnglishSymplectic Elements at Oxford1984Grant, AGreen, NHore, PMclauchlan, KAn explanation of some unexpected enchancements in the chemically induced dynamic electron polarization (CIDEP) spectra of ketyl radicals is suggested. It requires an electron exchange interaction that is negative for proximate radicals but positive for more distant ones and that geminate radical pairs are formed at a separation smaller than that at which random encounter pairs of the same radicals are able to react. © 1984. |
| spellingShingle | Grant, A Green, N Hore, P Mclauchlan, K SPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEP |
| title | SPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEP |
| title_full | SPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEP |
| title_fullStr | SPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEP |
| title_full_unstemmed | SPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEP |
| title_short | SPIN EXCHANGE EFFECTS IN RADICAL PAIR CIDEP |
| title_sort | spin exchange effects in radical pair cidep |
| work_keys_str_mv | AT granta spinexchangeeffectsinradicalpaircidep AT greenn spinexchangeeffectsinradicalpaircidep AT horep spinexchangeeffectsinradicalpaircidep AT mclauchlank spinexchangeeffectsinradicalpaircidep |