Mechanistic studies of the palladium-catalyzed desulfinative cross-coupling of aryl bromides and (hetero)aryl sulfinate salts

Mechanistic studies of the palladium-catalyzed desulfinative cross-coupling of aryl bromides and (hetero)aryl sulfinate salts

Pyridine and related heterocyclic sulfinates have recently emerged as effective nucleophilic coupling partners in palladium-catalyzed cross-coupling reactions with (hetero)aryl halides. These sulfinate reagents are straightforward to prepare, stable to storage and coupling reaction conditions, and d...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron:	de Gombert, A, McKay, AI, Davis, CJ, Wheelhouse KM, Willis, MC
Fformat:	Journal article
Iaith:	English
Cyhoeddwyd:	American Chemical Society 2020

Eitemau Tebyg

Copper-catalyzed synthesis of masked (hetero)aryl sulfinates
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Cyhoeddwyd: (2020)

One-pot sulfonamide synthesis exploiting the palladium-catalyzed sulfination of aryl iodides
gan: Flegeau, E, et al.
Cyhoeddwyd: (2015)

A General, Practical Palladium-Catalyzed Cyanation of (Hetero)Aryl Chlorides and Bromides
gan: Senecal, Todd D., et al.
Cyhoeddwyd: (2015)

The Pd-catalyzed fluorination of (hetero)aryl bromides and triflates
gan: Milner, Phillip J
Cyhoeddwyd: (2015)

Reductant-free cross-electrophile synthesis of di(hetero)arylmethanes by palladium-catalyzed desulfinative C–C coupling
gan: McKnight, J, et al.
Cyhoeddwyd: (2022)

Pyridine sulfinates as general nucleophilic coupling partners in palladium-catalyzed cross-coupling reactions with aryl halides
gan: Markovic, T, et al.
Cyhoeddwyd: (2017)

Palladium-catalysed desulfinative cross-coupling reactions: Leveraging mechanistic insights for reaction optimisation
gan: De Gombert, A
Cyhoeddwyd: (2021)

One-pot palladium-catalyzed synthesis of sulfonyl fluorides from aryl bromides
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Cyhoeddwyd: (2016)

Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
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Cyhoeddwyd: (2012)

Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
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Cyhoeddwyd: (2013)

Assembly of (hetero)aryl sulfilimines via copper-catalyzed enantioselective S-arylation of sulfenamides with (hetero)aryl Iodides
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Cyhoeddwyd: (2015)

Palladium-catalyzed alpha-arylation of oxindoles.
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Cyhoeddwyd: (2008)

A Nickel/Organoboron-Catalyzed Coupling of Aryl Bromides with Sodium Sulfinates: The Synthesis of Sulfones under Visible Light
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Cyhoeddwyd: (2024-07-01)

Palladium-catalyzed aminosulfonylation of aryl halides.
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Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media
gan: Cohen, Daniel Tzvi, et al.
Cyhoeddwyd: (2017)

Palladium-catalyzed synthesis of ammonium sulfinates from aryl halides and a sulfur dioxide surrogate: a gas- and reductant-free process.
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Palladium-Catalyzed N-Arylation of 2-Aminothiazoles
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The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides
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Nickel(II)-catalyzed synthesis of sulfinates from aryl and heteroaryl boronic acids and the sulfur dioxide surrogate DABSO
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Tandem Pd-Catalyzed Cyclization/Coupling of Non-Terminal Acetylenic Activated Methylenes with (Hetero)Aryl Bromides
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Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel
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Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides
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Palladium(II)-catalyzed synthesis of sulfinates from boronic acids and DABSO: a redox-neutral, phosphine-free transformation
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Cyhoeddwyd: (2016)

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Cyhoeddwyd: (2010)

Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
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Cyhoeddwyd: (2010-01-01)

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Cyhoeddwyd: (2013)

Palladium-Catalyzed Synthesis of N-Aryl Carbamates
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Cyhoeddwyd: (2015)

Palladium(0)-catalyzed arylative dearomatization of phenols.
gan: Rousseaux, S, et al.
Cyhoeddwyd: (2011)

Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles
gan: Jiao, Zhiwei, et al.
Cyhoeddwyd: (2017)

Palladium-Catalyzed Regioselective Arylation of Unprotected Allylamines
gan: Vinod G. Landge, et al.
Cyhoeddwyd: (2020-12-01)

Reactivity of bromoselenophenes in palladium-catalyzed direct arylations
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Palladium-catalyzed cyclobutenation of aryl chlorides with norbornenes
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Cyhoeddwyd: (2022-02-01)

Palladium-Catalysed Reductive Aminocarbonylation of Aryl Bromides and Iodides with Nitroarenes
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