Mechanistic studies of the palladium-catalyzed desulfinative cross-coupling of aryl bromides and (hetero)aryl sulfinate salts

Mechanistic studies of the palladium-catalyzed desulfinative cross-coupling of aryl bromides and (hetero)aryl sulfinate salts

Pyridine and related heterocyclic sulfinates have recently emerged as effective nucleophilic coupling partners in palladium-catalyzed cross-coupling reactions with (hetero)aryl halides. These sulfinate reagents are straightforward to prepare, stable to storage and coupling reaction conditions, and d...

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Bibliografiske detaljer
Main Authors:	de Gombert, A, McKay, AI, Davis, CJ, Wheelhouse KM, Willis, MC
Format:	Journal article
Sprog:	English
Udgivet:	American Chemical Society 2020

Lignende værker

Copper-catalyzed synthesis of masked (hetero)aryl sulfinates
af: Merino, MR, et al.
Udgivet: (2024)

Palladium-catalyzed desulfinative cross-couplings
af: de Gombert, A, et al.
Udgivet: (2020)

One-pot sulfonamide synthesis exploiting the palladium-catalyzed sulfination of aryl iodides
af: Flegeau, E, et al.
Udgivet: (2015)

A General, Practical Palladium-Catalyzed Cyanation of (Hetero)Aryl Chlorides and Bromides
af: Senecal, Todd D., et al.
Udgivet: (2015)

The Pd-catalyzed fluorination of (hetero)aryl bromides and triflates
af: Milner, Phillip J
Udgivet: (2015)

Reductant-free cross-electrophile synthesis of di(hetero)arylmethanes by palladium-catalyzed desulfinative C–C coupling
af: McKnight, J, et al.
Udgivet: (2022)

Pyridine sulfinates as general nucleophilic coupling partners in palladium-catalyzed cross-coupling reactions with aryl halides
af: Markovic, T, et al.
Udgivet: (2017)

Palladium-catalysed desulfinative cross-coupling reactions: Leveraging mechanistic insights for reaction optimisation
af: De Gombert, A
Udgivet: (2021)

One-pot palladium-catalyzed synthesis of sulfonyl fluorides from aryl bromides
af: Davies, A, et al.
Udgivet: (2016)

Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
af: Shen, Xiaoqiang, et al.
Udgivet: (2012)

Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
af: Pan, Jun, et al.
Udgivet: (2013)

Assembly of (hetero)aryl sulfilimines via copper-catalyzed enantioselective S-arylation of sulfenamides with (hetero)aryl Iodides
af: Mingchuang He, et al.
Udgivet: (2025-03-01)

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst
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Udgivet: (2015)

Palladium-catalyzed alpha-arylation of oxindoles.
af: Durbin, M, et al.
Udgivet: (2008)

A Nickel/Organoboron-Catalyzed Coupling of Aryl Bromides with Sodium Sulfinates: The Synthesis of Sulfones under Visible Light
af: Siyi Ding, et al.
Udgivet: (2024-07-01)

Palladium-catalyzed aminosulfonylation of aryl halides.
af: Nguyen, B, et al.
Udgivet: (2010)

Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media
af: Cohen, Daniel Tzvi, et al.
Udgivet: (2017)

Palladium-catalyzed synthesis of ammonium sulfinates from aryl halides and a sulfur dioxide surrogate: a gas- and reductant-free process.
af: Emmett, E, et al.
Udgivet: (2014)

Palladium-Catalyzed Esterification of Aryl Fluorosulfates with Aryl Formates
af: Xue Chen, et al.
Udgivet: (2024-04-01)

Carbon-trifluoromethyl bond forming reactions and palladium-catalyzed cyanation of (hetero)aryl halides
af: Senecal, Todd D. (Todd Dale)
Udgivet: (2013)

Rhodium-catalyzed selective direct arylation of phosphines with aryl bromides
af: Dingyi Wang, et al.
Udgivet: (2022-05-01)

Intramolecular palladium-catalyzed direct arylation of alkenyl triflates.
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Udgivet: (2007)

Palladium-Catalyzed N-Arylation of 2-Aminothiazoles
af: McGowan, Meredeth A., et al.
Udgivet: (2013)

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides
af: Cho, Eun Jin, et al.
Udgivet: (2013)

Nickel(II)-catalyzed synthesis of sulfinates from aryl and heteroaryl boronic acids and the sulfur dioxide surrogate DABSO
af: Willis, M, et al.
Udgivet: (2019)

Tandem Pd-Catalyzed Cyclization/Coupling of Non-Terminal Acetylenic Activated Methylenes with (Hetero)Aryl Bromides
af: Aleksandra Błocka, et al.
Udgivet: (2022-01-01)

Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel
af: Chang Xu, et al.
Udgivet: (2018-03-01)

Palladium-Catalyzed Addition of Aryl Halides to N ‑Sulfinylamines for the Synthesis of Sulfinamides
af: Wei, M, et al.
Udgivet: (2024)

Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides
af: Lee, Hong Geun, et al.
Udgivet: (2015)

Palladium(II)-catalyzed synthesis of sulfinates from boronic acids and DABSO: a redox-neutral, phosphine-free transformation
af: Deeming, AS, et al.
Udgivet: (2016)

Intramolecular palladium-catalyzed alkane C-H arylation from aryl chlorides.
af: Rousseaux, S, et al.
Udgivet: (2010)

Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
af: İsmail Özdemir, et al.
Udgivet: (2010-01-01)

Palladium(0)-Catalyzed Arylative Dearomatization of Phenols
af: Rousseaux, Sophie, et al.
Udgivet: (2013)

Palladium-Catalyzed Synthesis of N-Aryl Carbamates
af: Fors, Brett P., et al.
Udgivet: (2015)

Palladium(0)-catalyzed arylative dearomatization of phenols.
af: Rousseaux, S, et al.
Udgivet: (2011)

Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles
af: Jiao, Zhiwei, et al.
Udgivet: (2017)

Palladium-Catalyzed Regioselective Arylation of Unprotected Allylamines
af: Vinod G. Landge, et al.
Udgivet: (2020-12-01)

Reactivity of bromoselenophenes in palladium-catalyzed direct arylations
af: Aymen Skhiri, et al.
Udgivet: (2017-12-01)

Palladium-catalyzed cyclobutenation of aryl chlorides with norbornenes
af: Zhenkun Chen, et al.
Udgivet: (2022-02-01)

Palladium-Catalysed Reductive Aminocarbonylation of Aryl Bromides and Iodides with Nitroarenes
af: Blessing D. Mkhonazi, et al.
Udgivet: (2022-09-01)