2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.

Amine for it! A cationic rhodium catalyst, which was assembled insitu from commercial components, promoted the reaction of a range of simple 2-aminobenzaldehydes with terminal and internal alkynes in a series of intermolecular hydroacylation reactions. The products of this reaction, amino-substitute...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों: Castaing, M, Wason, S, Estepa, B, Hooper, J, Willis, M
स्वरूप: Journal article
भाषा:English
प्रकाशित: 2013
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author Castaing, M
Wason, S
Estepa, B
Hooper, J
Willis, M
author_facet Castaing, M
Wason, S
Estepa, B
Hooper, J
Willis, M
author_sort Castaing, M
collection OXFORD
description Amine for it! A cationic rhodium catalyst, which was assembled insitu from commercial components, promoted the reaction of a range of simple 2-aminobenzaldehydes with terminal and internal alkynes in a series of intermolecular hydroacylation reactions. The products of this reaction, amino-substituted enones, were efficiently converted into the corresponding dihydro-4-quinolones. © 2013 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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spelling oxford-uuid:3d6b968c-87c0-4317-97fa-6853daa8c1a62022-03-26T14:19:14Z2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3d6b968c-87c0-4317-97fa-6853daa8c1a6EnglishSymplectic Elements at Oxford2013Castaing, MWason, SEstepa, BHooper, JWillis, MAmine for it! A cationic rhodium catalyst, which was assembled insitu from commercial components, promoted the reaction of a range of simple 2-aminobenzaldehydes with terminal and internal alkynes in a series of intermolecular hydroacylation reactions. The products of this reaction, amino-substituted enones, were efficiently converted into the corresponding dihydro-4-quinolones. © 2013 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Castaing, M
Wason, S
Estepa, B
Hooper, J
Willis, M
2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
title 2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
title_full 2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
title_fullStr 2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
title_full_unstemmed 2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
title_short 2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
title_sort 2 aminobenzaldehydes as versatile substrates for rhodium catalyzed alkyne hydroacylation application to dihydroquinolone synthesis
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AT wasons 2aminobenzaldehydesasversatilesubstratesforrhodiumcatalyzedalkynehydroacylationapplicationtodihydroquinolonesynthesis
AT estepab 2aminobenzaldehydesasversatilesubstratesforrhodiumcatalyzedalkynehydroacylationapplicationtodihydroquinolonesynthesis
AT hooperj 2aminobenzaldehydesasversatilesubstratesforrhodiumcatalyzedalkynehydroacylationapplicationtodihydroquinolonesynthesis
AT willism 2aminobenzaldehydesasversatilesubstratesforrhodiumcatalyzedalkynehydroacylationapplicationtodihydroquinolonesynthesis