The influence of nitrogen on dislocation locking in float-zone silicon

Dislocation locking by nitrogen impurities has been investigated in float-zone silicon with nitrogen concentrations of 2.2 × 10 15cm-3 and 3 × 1014cm-3. The stress required to unlock dislocations pinned by nitrogen impurities was measured as a function of annealing time (0 to 2500 hours) and tempera...

Full description

Bibliographic Details
Main Authors: Murphy, J, Giannattasio, A, Alpass, C, Senkader, S, Falster, R, Wilshaw, P
Format: Journal article
Language:English
Published: Trans Tech Publications Ltd 2005
_version_ 1826268416971898880
author Murphy, J
Giannattasio, A
Alpass, C
Senkader, S
Falster, R
Wilshaw, P
author_facet Murphy, J
Giannattasio, A
Alpass, C
Senkader, S
Falster, R
Wilshaw, P
author_sort Murphy, J
collection OXFORD
description Dislocation locking by nitrogen impurities has been investigated in float-zone silicon with nitrogen concentrations of 2.2 × 10 15cm-3 and 3 × 1014cm-3. The stress required to unlock dislocations pinned by nitrogen impurities was measured as a function of annealing time (0 to 2500 hours) and temperature (550 to 830°C). For all conditions investigated the locking effect was found to increase linearly with annealing time before saturating. It is assumed that the rate of increase of unlocking stress with annealing time is a measure of transport of nitrogen to the dislocation core. This rate of increase was found to depend linearly on nitrogen concentration, which is consistent with transport by a dimeric species, whose activation energy for diffusion is approximately 1.4eV. The saturation unlocking stress has been found to be dependent on the nitrogen concentration. Additionally, the temperature dependence of the stress required to move dislocations immobilised by nitrogen impurities has been studied. By assuming a value for the binding energy of the nitrogen to the dislocation, the density of the locking species at the dislocation core has been calculated.
first_indexed 2024-03-06T21:09:21Z
format Journal article
id oxford-uuid:3d9a344f-2fae-4801-90af-e595cfb25834
institution University of Oxford
language English
last_indexed 2024-03-06T21:09:21Z
publishDate 2005
publisher Trans Tech Publications Ltd
record_format dspace
spelling oxford-uuid:3d9a344f-2fae-4801-90af-e595cfb258342022-03-26T14:20:26ZThe influence of nitrogen on dislocation locking in float-zone siliconJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3d9a344f-2fae-4801-90af-e595cfb25834EnglishSymplectic Elements at OxfordTrans Tech Publications Ltd2005Murphy, JGiannattasio, AAlpass, CSenkader, SFalster, RWilshaw, PDislocation locking by nitrogen impurities has been investigated in float-zone silicon with nitrogen concentrations of 2.2 × 10 15cm-3 and 3 × 1014cm-3. The stress required to unlock dislocations pinned by nitrogen impurities was measured as a function of annealing time (0 to 2500 hours) and temperature (550 to 830°C). For all conditions investigated the locking effect was found to increase linearly with annealing time before saturating. It is assumed that the rate of increase of unlocking stress with annealing time is a measure of transport of nitrogen to the dislocation core. This rate of increase was found to depend linearly on nitrogen concentration, which is consistent with transport by a dimeric species, whose activation energy for diffusion is approximately 1.4eV. The saturation unlocking stress has been found to be dependent on the nitrogen concentration. Additionally, the temperature dependence of the stress required to move dislocations immobilised by nitrogen impurities has been studied. By assuming a value for the binding energy of the nitrogen to the dislocation, the density of the locking species at the dislocation core has been calculated.
spellingShingle Murphy, J
Giannattasio, A
Alpass, C
Senkader, S
Falster, R
Wilshaw, P
The influence of nitrogen on dislocation locking in float-zone silicon
title The influence of nitrogen on dislocation locking in float-zone silicon
title_full The influence of nitrogen on dislocation locking in float-zone silicon
title_fullStr The influence of nitrogen on dislocation locking in float-zone silicon
title_full_unstemmed The influence of nitrogen on dislocation locking in float-zone silicon
title_short The influence of nitrogen on dislocation locking in float-zone silicon
title_sort influence of nitrogen on dislocation locking in float zone silicon
work_keys_str_mv AT murphyj theinfluenceofnitrogenondislocationlockinginfloatzonesilicon
AT giannattasioa theinfluenceofnitrogenondislocationlockinginfloatzonesilicon
AT alpassc theinfluenceofnitrogenondislocationlockinginfloatzonesilicon
AT senkaders theinfluenceofnitrogenondislocationlockinginfloatzonesilicon
AT falsterr theinfluenceofnitrogenondislocationlockinginfloatzonesilicon
AT wilshawp theinfluenceofnitrogenondislocationlockinginfloatzonesilicon
AT murphyj influenceofnitrogenondislocationlockinginfloatzonesilicon
AT giannattasioa influenceofnitrogenondislocationlockinginfloatzonesilicon
AT alpassc influenceofnitrogenondislocationlockinginfloatzonesilicon
AT senkaders influenceofnitrogenondislocationlockinginfloatzonesilicon
AT falsterr influenceofnitrogenondislocationlockinginfloatzonesilicon
AT wilshawp influenceofnitrogenondislocationlockinginfloatzonesilicon