Devolatilization of subducting slabs, part II: volatile fluxes and storage

<p>Subduction is a crucial part of the long‐term water and carbon cycling between Earth's exosphere and interior. However, there is broad disagreement over how much water and carbon is liberated from subducting slabs to the mantle wedge and transported to island‐arc volcanoes. In the comp...

Description complète

Détails bibliographiques
Auteurs principaux: Tian, M, Katz, R, Rees Jones, D, May, D
Format: Journal article
Langue:English
Publié: American Geophysical Union 2019
_version_ 1826268498899238912
author Tian, M
Katz, R
Rees Jones, D
May, D
author_facet Tian, M
Katz, R
Rees Jones, D
May, D
author_sort Tian, M
collection OXFORD
description <p>Subduction is a crucial part of the long‐term water and carbon cycling between Earth's exosphere and interior. However, there is broad disagreement over how much water and carbon is liberated from subducting slabs to the mantle wedge and transported to island‐arc volcanoes. In the companion paper Part I, we parameterize the metamorphic reactions involving H<sub>2</sub>O and CO<sub>2</sub> for representative subducting lithologies. On this basis, a two‐dimensional reactive transport model is constructed in this Part II. We assess the various controlling factors of CO<sub>2</sub> and H<sub>2</sub>O release from subducting slabs. Model results show that up‐slab fluid flow directions produce a flux peak of CO<sub>2</sub> and H<sub>2</sub>O at subarc depths. Moreover, infiltration of H<sub>2</sub>O‐rich fluids sourced from hydrated slab mantle enhances decarbonation or carbonation at lithological interfaces, increases slab surface fluxes, and redistributes CO<sub>2</sub> from basalt and gabbro layers to the overlying sedimentary layer. As a result, removal of the cap sediments (by diapirism or off‐scraping) leads to elevated slab surface CO<sub>2</sub> and H<sub>2</sub>O fluxes. The modelled subduction efficiency (the percentage of initially subducted volatiles retained until ~200 km deep) of H<sub>2</sub>O and CO<sub>2</sub> is increased by open‐system effects due to fractionation within the interior of lithological layers.</p>
first_indexed 2024-03-06T21:10:37Z
format Journal article
id oxford-uuid:3e04a805-6b7c-4102-a4fa-dfa12011331a
institution University of Oxford
language English
last_indexed 2024-03-06T21:10:37Z
publishDate 2019
publisher American Geophysical Union
record_format dspace
spelling oxford-uuid:3e04a805-6b7c-4102-a4fa-dfa12011331a2022-03-26T14:22:59ZDevolatilization of subducting slabs, part II: volatile fluxes and storageJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3e04a805-6b7c-4102-a4fa-dfa12011331aEnglishSymplectic Elements at OxfordAmerican Geophysical Union2019Tian, MKatz, RRees Jones, DMay, D<p>Subduction is a crucial part of the long‐term water and carbon cycling between Earth's exosphere and interior. However, there is broad disagreement over how much water and carbon is liberated from subducting slabs to the mantle wedge and transported to island‐arc volcanoes. In the companion paper Part I, we parameterize the metamorphic reactions involving H<sub>2</sub>O and CO<sub>2</sub> for representative subducting lithologies. On this basis, a two‐dimensional reactive transport model is constructed in this Part II. We assess the various controlling factors of CO<sub>2</sub> and H<sub>2</sub>O release from subducting slabs. Model results show that up‐slab fluid flow directions produce a flux peak of CO<sub>2</sub> and H<sub>2</sub>O at subarc depths. Moreover, infiltration of H<sub>2</sub>O‐rich fluids sourced from hydrated slab mantle enhances decarbonation or carbonation at lithological interfaces, increases slab surface fluxes, and redistributes CO<sub>2</sub> from basalt and gabbro layers to the overlying sedimentary layer. As a result, removal of the cap sediments (by diapirism or off‐scraping) leads to elevated slab surface CO<sub>2</sub> and H<sub>2</sub>O fluxes. The modelled subduction efficiency (the percentage of initially subducted volatiles retained until ~200 km deep) of H<sub>2</sub>O and CO<sub>2</sub> is increased by open‐system effects due to fractionation within the interior of lithological layers.</p>
spellingShingle Tian, M
Katz, R
Rees Jones, D
May, D
Devolatilization of subducting slabs, part II: volatile fluxes and storage
title Devolatilization of subducting slabs, part II: volatile fluxes and storage
title_full Devolatilization of subducting slabs, part II: volatile fluxes and storage
title_fullStr Devolatilization of subducting slabs, part II: volatile fluxes and storage
title_full_unstemmed Devolatilization of subducting slabs, part II: volatile fluxes and storage
title_short Devolatilization of subducting slabs, part II: volatile fluxes and storage
title_sort devolatilization of subducting slabs part ii volatile fluxes and storage
work_keys_str_mv AT tianm devolatilizationofsubductingslabspartiivolatilefluxesandstorage
AT katzr devolatilizationofsubductingslabspartiivolatilefluxesandstorage
AT reesjonesd devolatilizationofsubductingslabspartiivolatilefluxesandstorage
AT mayd devolatilizationofsubductingslabspartiivolatilefluxesandstorage