Cation-directed atropselective synthesis of BINOL derivatives
<p>The use of chiral counterions to facilitate enantioselective mono-<em>C</em>-alkylation of enolates has been explored extensively over the past century. We have demonstrated that an alternative mode of reactivity – <em>O</em>-alkylation – predominates if the <em...
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| 格式: | Thesis |
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2017
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