Atomic resolution imaging and topography of boron nitride sheets produced by chemical exfoliation

Here, we present a simple method for preparing thin few-layer sheets of hexagonal BN with micrometer-sized dimensions using chemical exfoliation in the solvent 1,2-dichloroethane. The atomic structure of both few-layer and monolayer BN sheets is directly imaged using aberration-corrected high-resolu...

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Príomhchruthaitheoirí: Warner, J, Rümmeli, M, Bachmatiuk, A, Büchner, B
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2010
Cur síos
Achoimre:Here, we present a simple method for preparing thin few-layer sheets of hexagonal BN with micrometer-sized dimensions using chemical exfoliation in the solvent 1,2-dichloroethane. The atomic structure of both few-layer and monolayer BN sheets is directly imaged using aberration-corrected high-resolution transmission electron microscopy. Electron beam induced sputtering effects are examined in real time. The removal of layers of BN by electron beam irradiation leads to the exposure of a step edge between a monolayer and bilayer region. We use HRTEM imaging combined with image simulations to show that BN bilayers can have AB stacking and are not limited to just AA stacking. © 2010 American Chemical Society.