Atomic level structural and chemical analysis of Cr-doped Bi₂Se₃

We present a study of the structure and chemical composition of the Cr-doped 3D topological insulator Bi2Se3. Single-crystalline thin films were grown by molecular beam epitaxy on Al2O3 (0001), and their structural and chemical properties determined on an atomic level by aberration-corrected scannin...

Full description

Bibliographic Details
Main Authors: Ghasemi, A, Kepaptsoglou, D, Collins-McIntyre, L, Ramasse, Q, Hesjedal, T, Lazarov, V
Format: Journal article
Published: Nature Publishing Group 2016
_version_ 1797064370021203968
author Ghasemi, A
Kepaptsoglou, D
Collins-McIntyre, L
Ramasse, Q
Hesjedal, T
Lazarov, V
author_facet Ghasemi, A
Kepaptsoglou, D
Collins-McIntyre, L
Ramasse, Q
Hesjedal, T
Lazarov, V
author_sort Ghasemi, A
collection OXFORD
description We present a study of the structure and chemical composition of the Cr-doped 3D topological insulator Bi2Se3. Single-crystalline thin films were grown by molecular beam epitaxy on Al2O3 (0001), and their structural and chemical properties determined on an atomic level by aberration-corrected scanning transmission electron microscopy and electron energy loss spectroscopy. A regular quintuple layer stacking of the Bi2Se3 film is found, with the exception of the first several atomic layers in the initial growth. The spectroscopy data give direct evidence that Cr is preferentially substituting for Bi in the Bi2Se3 host. We also show that Cr has a tendency to segregate at internal grain boundaries of the Bi2Se3 film.
first_indexed 2024-03-06T21:13:18Z
format Journal article
id oxford-uuid:3eea349a-9b98-49b9-a27d-6201624a824c
institution University of Oxford
last_indexed 2024-03-06T21:13:18Z
publishDate 2016
publisher Nature Publishing Group
record_format dspace
spelling oxford-uuid:3eea349a-9b98-49b9-a27d-6201624a824c2022-03-26T14:28:36ZAtomic level structural and chemical analysis of Cr-doped Bi₂Se₃Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3eea349a-9b98-49b9-a27d-6201624a824cSymplectic Elements at OxfordNature Publishing Group2016Ghasemi, AKepaptsoglou, DCollins-McIntyre, LRamasse, QHesjedal, TLazarov, VWe present a study of the structure and chemical composition of the Cr-doped 3D topological insulator Bi2Se3. Single-crystalline thin films were grown by molecular beam epitaxy on Al2O3 (0001), and their structural and chemical properties determined on an atomic level by aberration-corrected scanning transmission electron microscopy and electron energy loss spectroscopy. A regular quintuple layer stacking of the Bi2Se3 film is found, with the exception of the first several atomic layers in the initial growth. The spectroscopy data give direct evidence that Cr is preferentially substituting for Bi in the Bi2Se3 host. We also show that Cr has a tendency to segregate at internal grain boundaries of the Bi2Se3 film.
spellingShingle Ghasemi, A
Kepaptsoglou, D
Collins-McIntyre, L
Ramasse, Q
Hesjedal, T
Lazarov, V
Atomic level structural and chemical analysis of Cr-doped Bi₂Se₃
title Atomic level structural and chemical analysis of Cr-doped Bi₂Se₃
title_full Atomic level structural and chemical analysis of Cr-doped Bi₂Se₃
title_fullStr Atomic level structural and chemical analysis of Cr-doped Bi₂Se₃
title_full_unstemmed Atomic level structural and chemical analysis of Cr-doped Bi₂Se₃
title_short Atomic level structural and chemical analysis of Cr-doped Bi₂Se₃
title_sort atomic level structural and chemical analysis of cr doped bi₂se₃
work_keys_str_mv AT ghasemia atomiclevelstructuralandchemicalanalysisofcrdopedbi2se3
AT kepaptsogloud atomiclevelstructuralandchemicalanalysisofcrdopedbi2se3
AT collinsmcintyrel atomiclevelstructuralandchemicalanalysisofcrdopedbi2se3
AT ramasseq atomiclevelstructuralandchemicalanalysisofcrdopedbi2se3
AT hesjedalt atomiclevelstructuralandchemicalanalysisofcrdopedbi2se3
AT lazarovv atomiclevelstructuralandchemicalanalysisofcrdopedbi2se3