Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes
We report that the use of catalytic quantities of hypervalent iodine reagents (PIDA or Dess Martin Periodinane) allows the rapid and stereoselective formation of cyclobutanes under very mild conditions. The presence of a fluorinated solvent is essential for the success of these reactions which are a...
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| Format: | Journal article |
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Wiley
2016
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| _version_ | 1826268755805601792 |
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| author | Donohoe, T Colomer, I Coura Barcelos, R |
| author_facet | Donohoe, T Colomer, I Coura Barcelos, R |
| author_sort | Donohoe, T |
| collection | OXFORD |
| description | We report that the use of catalytic quantities of hypervalent iodine reagents (PIDA or Dess Martin Periodinane) allows the rapid and stereoselective formation of cyclobutanes under very mild conditions. The presence of a fluorinated solvent is essential for the success of these reactions which are able to form unsymmetrical tri- and tetrasubstituted cyclobutanes via a heterodimerisation process involving two different alkenes. |
| first_indexed | 2024-03-06T21:14:28Z |
| format | Journal article |
| id | oxford-uuid:3f49caea-2d02-4ba2-b831-fcbb0e62c5b2 |
| institution | University of Oxford |
| last_indexed | 2024-03-06T21:14:28Z |
| publishDate | 2016 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:3f49caea-2d02-4ba2-b831-fcbb0e62c5b22022-03-26T14:31:08ZCatalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted CyclobutanesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3f49caea-2d02-4ba2-b831-fcbb0e62c5b2Symplectic Elements at OxfordWiley2016Donohoe, TColomer, ICoura Barcelos, RWe report that the use of catalytic quantities of hypervalent iodine reagents (PIDA or Dess Martin Periodinane) allows the rapid and stereoselective formation of cyclobutanes under very mild conditions. The presence of a fluorinated solvent is essential for the success of these reactions which are able to form unsymmetrical tri- and tetrasubstituted cyclobutanes via a heterodimerisation process involving two different alkenes. |
| spellingShingle | Donohoe, T Colomer, I Coura Barcelos, R Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes |
| title | Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes |
| title_full | Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes |
| title_fullStr | Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes |
| title_full_unstemmed | Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes |
| title_short | Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes |
| title_sort | catalytic hypervalent iodine promoters lead to styrene dimerization and the formation of tri and tetrasubstituted cyclobutanes |
| work_keys_str_mv | AT donohoet catalytichypervalentiodinepromotersleadtostyrenedimerizationandtheformationoftriandtetrasubstitutedcyclobutanes AT colomeri catalytichypervalentiodinepromotersleadtostyrenedimerizationandtheformationoftriandtetrasubstitutedcyclobutanes AT courabarcelosr catalytichypervalentiodinepromotersleadtostyrenedimerizationandtheformationoftriandtetrasubstitutedcyclobutanes |