Shape-tuning the colloidal assemblies in nematic liquid crystals

Colloidal platelets are natural building blocks for the shape-controlled assembly of two-dimensional periodic lattices and can form versatile optical elements. Using three-dimensional (3D) numerical modelling, we demonstrate the self-assembly of triangular, square and pentagonal sub-micrometer sized...

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Những tác giả chính: Dontabhaktuni, J, Ravnik, M, Zumer, S
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2012
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author Dontabhaktuni, J
Ravnik, M
Zumer, S
author_facet Dontabhaktuni, J
Ravnik, M
Zumer, S
author_sort Dontabhaktuni, J
collection OXFORD
description Colloidal platelets are natural building blocks for the shape-controlled assembly of two-dimensional periodic lattices and can form versatile optical elements. Using three-dimensional (3D) numerical modelling, we demonstrate the self-assembly of triangular, square and pentagonal sub-micrometer sized platelets in a thin layer of nematic liquid crystal. Torques acting on individual platelets are calculated, showing that platelets with quadrupolar symmetry (squares, hexagons, etc) are, orientationally, more strongly bound than platelets with dipolar symmetry (triangles, pentagons) which is important for switching applications. Inter-platelet potentials are shown to depend in a complex way on the orientations of the platelets, exhibiting easy and hard reorientation axes and multiple minima. Linear chains of elastic dipoles form into two-dimensional periodic lattices via interesting rotational and translational shifts, to minimize the distortions in the surrounding nematic medium. © 2012 The Royal Society of Chemistry.
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spelling oxford-uuid:3f542f15-19f9-4df2-96b4-ff6de70457512022-03-26T14:31:19ZShape-tuning the colloidal assemblies in nematic liquid crystalsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3f542f15-19f9-4df2-96b4-ff6de7045751EnglishSymplectic Elements at Oxford2012Dontabhaktuni, JRavnik, MZumer, SColloidal platelets are natural building blocks for the shape-controlled assembly of two-dimensional periodic lattices and can form versatile optical elements. Using three-dimensional (3D) numerical modelling, we demonstrate the self-assembly of triangular, square and pentagonal sub-micrometer sized platelets in a thin layer of nematic liquid crystal. Torques acting on individual platelets are calculated, showing that platelets with quadrupolar symmetry (squares, hexagons, etc) are, orientationally, more strongly bound than platelets with dipolar symmetry (triangles, pentagons) which is important for switching applications. Inter-platelet potentials are shown to depend in a complex way on the orientations of the platelets, exhibiting easy and hard reorientation axes and multiple minima. Linear chains of elastic dipoles form into two-dimensional periodic lattices via interesting rotational and translational shifts, to minimize the distortions in the surrounding nematic medium. © 2012 The Royal Society of Chemistry.
spellingShingle Dontabhaktuni, J
Ravnik, M
Zumer, S
Shape-tuning the colloidal assemblies in nematic liquid crystals
title Shape-tuning the colloidal assemblies in nematic liquid crystals
title_full Shape-tuning the colloidal assemblies in nematic liquid crystals
title_fullStr Shape-tuning the colloidal assemblies in nematic liquid crystals
title_full_unstemmed Shape-tuning the colloidal assemblies in nematic liquid crystals
title_short Shape-tuning the colloidal assemblies in nematic liquid crystals
title_sort shape tuning the colloidal assemblies in nematic liquid crystals
work_keys_str_mv AT dontabhaktunij shapetuningthecolloidalassembliesinnematicliquidcrystals
AT ravnikm shapetuningthecolloidalassembliesinnematicliquidcrystals
AT zumers shapetuningthecolloidalassembliesinnematicliquidcrystals