trans-Hydroboration–oxidation products in Δ5-steroids via a hydroboration-retro-hydroboration mechanism

Herein, we report for the first time a “trans-hydroboration–oxidation product” isolated and characterized under traditional hydroboration–oxidation conditions using cholesterol and diosgenin as substrates. These substrates are excellent starting materials because of the rigidity and different struct...

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Main Authors: Hilario-Martínez, JC, Murillo, F, García-Méndez, J, Dzib, E, Sandoval-Ramírez, J, Muñoz-Hernández, MÁ, Bernès, S, Kürti, L, Duarte Gonzalez, FJ, Merino, G, Fernández-Herrera, MA
格式: Journal article
语言:English
出版: Royal Society of Chemistry 2020