Deprotonation of group 14 metal amide complexes bearing ditopic carbanionic n-heterocyclic carbene ligands. Constitutional isomerism and dynamic behavior
The reactivity of the lithiated N-heterocyclic carbene [:C[N(2,6- i Pr 2 C 6 H 3 )] 2 (CH)CLi] ∞ with two-coordinate homoleptic group 14 amides E[N(SiMe 3 ) 2 ] 2 (E = Sn, Pb) is described. Solutions of these mixtures readily result in the formal loss of 1 equiv of bis(trimethylsilyl)amine, HN(SiMe...
| Main Authors: | , , |
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| Format: | Journal article |
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American Chemical Society
2017
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