Volatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatism

Deep-Earth volatile cycles couple the mantle with near-surface reservoirs. Volatiles are emitted by volcanism and, in particular, from mid-ocean ridges, which are the most prolific source of basaltic volcanism. Estimates of volatile extraction from the asthenosphere beneath ridges typically rely on...

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Main Authors: Keller, T, Katz, R, Hirschmann, M
Format: Journal article
Published: Elsevier 2017
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author Keller, T
Katz, R
Hirschmann, M
author_facet Keller, T
Katz, R
Hirschmann, M
author_sort Keller, T
collection OXFORD
description Deep-Earth volatile cycles couple the mantle with near-surface reservoirs. Volatiles are emitted by volcanism and, in particular, from mid-ocean ridges, which are the most prolific source of basaltic volcanism. Estimates of volatile extraction from the asthenosphere beneath ridges typically rely on measurements of undegassed lavas combined with simple petrogenetic models of the mean degree of melting. Estimated volatile fluxes have large uncertainties; this is partly due to a poor understanding of how volatiles are transported by magma in the asthenosphere. Here, we assess the fate of mantle volatiles through numerical simulations of melting and melt transport at mid-ocean ridges. Our simulations are based on two-phase, magma/mantle dynamics theory coupled to an idealised thermodynamic model of mantle melting in the presence of water and carbon dioxide. We combine simulation results with catalogued observations of all ridge segments to estimate a range of likely volatile output from the global mid-ocean ridge system. We thus predict global MOR crust production of 63-73 Gt/yr (21-24 km3/yr) and global volatile output of 29-110 Mt/yr, corresponding to mantle volatile contents of 50-200 ppm. We find that volatile extraction is limited: up to half of deep, volatile-rich melt is not focused to the axis but is rather deposited along the LAB. As these distal melts crystallise and fractionate, they metasomatise the base of the lithosphere, creating rheological heterogeneity that could contribute to the seismic signature of the LAB.
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spelling oxford-uuid:40f6d731-264e-4f3f-aff6-cdcabc4807a62022-03-26T14:40:51ZVolatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatismJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:40f6d731-264e-4f3f-aff6-cdcabc4807a6Symplectic Elements at OxfordElsevier2017Keller, TKatz, RHirschmann, MDeep-Earth volatile cycles couple the mantle with near-surface reservoirs. Volatiles are emitted by volcanism and, in particular, from mid-ocean ridges, which are the most prolific source of basaltic volcanism. Estimates of volatile extraction from the asthenosphere beneath ridges typically rely on measurements of undegassed lavas combined with simple petrogenetic models of the mean degree of melting. Estimated volatile fluxes have large uncertainties; this is partly due to a poor understanding of how volatiles are transported by magma in the asthenosphere. Here, we assess the fate of mantle volatiles through numerical simulations of melting and melt transport at mid-ocean ridges. Our simulations are based on two-phase, magma/mantle dynamics theory coupled to an idealised thermodynamic model of mantle melting in the presence of water and carbon dioxide. We combine simulation results with catalogued observations of all ridge segments to estimate a range of likely volatile output from the global mid-ocean ridge system. We thus predict global MOR crust production of 63-73 Gt/yr (21-24 km3/yr) and global volatile output of 29-110 Mt/yr, corresponding to mantle volatile contents of 50-200 ppm. We find that volatile extraction is limited: up to half of deep, volatile-rich melt is not focused to the axis but is rather deposited along the LAB. As these distal melts crystallise and fractionate, they metasomatise the base of the lithosphere, creating rheological heterogeneity that could contribute to the seismic signature of the LAB.
spellingShingle Keller, T
Katz, R
Hirschmann, M
Volatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatism
title Volatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatism
title_full Volatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatism
title_fullStr Volatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatism
title_full_unstemmed Volatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatism
title_short Volatiles beneath mid-ocean ridges: Deep melting, channelised transport, focusing, and metasomatism
title_sort volatiles beneath mid ocean ridges deep melting channelised transport focusing and metasomatism
work_keys_str_mv AT kellert volatilesbeneathmidoceanridgesdeepmeltingchannelisedtransportfocusingandmetasomatism
AT katzr volatilesbeneathmidoceanridgesdeepmeltingchannelisedtransportfocusingandmetasomatism
AT hirschmannm volatilesbeneathmidoceanridgesdeepmeltingchannelisedtransportfocusingandmetasomatism