[V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.

The bimetallic complex [V(Cp)]2Pn, containing a V-V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.

Bibliographic Details
Main Authors: Jones, S, O'Hare, D
Format: Journal article
Language:English
Published: 2003
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author Jones, S
O'Hare, D
author_facet Jones, S
O'Hare, D
author_sort Jones, S
collection OXFORD
description The bimetallic complex [V(Cp)]2Pn, containing a V-V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.
first_indexed 2024-03-06T21:19:50Z
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spelling oxford-uuid:41133f39-6b7d-44d8-a0af-a0b8db5364512022-03-26T14:41:30Z[V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:41133f39-6b7d-44d8-a0af-a0b8db536451EnglishSymplectic Elements at Oxford2003Jones, SO'Hare, DThe bimetallic complex [V(Cp)]2Pn, containing a V-V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.
spellingShingle Jones, S
O'Hare, D
[V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
title [V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
title_full [V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
title_fullStr [V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
title_full_unstemmed [V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
title_short [V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
title_sort v eta5 c5h5 2c8h6 a bimetallic pentalene bridged complex with multiple bonding between the metal atoms
work_keys_str_mv AT joness veta5c5h52c8h6abimetallicpentalenebridgedcomplexwithmultiplebondingbetweenthemetalatoms
AT ohared veta5c5h52c8h6abimetallicpentalenebridgedcomplexwithmultiplebondingbetweenthemetalatoms