Particle-modified electrodes: General mass transport theory, experimental validation, and the role of electrostatics

Particle-modified electrodes: General mass transport theory, experimental validation, and the role of electrostatics

We present general mass transport theory for cyclic voltammetry at electrodes that are partially ‘blocked’ with electrochemically-inactive particles. It is broadly applicable covering reversible, quasi-reversible, and irreversible reactions and is experimentally validated using the hydrazine oxidati...

Bibliografski detalji
Glavni autori:	Chen, L, Kätelhön, E, Compton, R
Format:	Journal article
Jezik:	English
Izdano:	Elsevier 2019

Slični predmeti

Hydrodynamics and mass transport in wall-tube and microjet electrodes: An experimental evaluation of current theory
od: Rees, N, i dr.
Izdano: (2003)

Electrode-particle impacts: a users guide
od: Sokolov, S, i dr.
Izdano: (2016)

Investigations into the role of electrostatics in the transport of dust particles
od: Lacks Daniel
Izdano: (2024-01-01)

Reversible voltammetry at cylindrical electrodes: Validity of a one-dimensional model
od: Le, H, i dr.
Izdano: (2020)

When does near-wall hindered diffusion influence mass transport towards targets?
od: Eloul, S, i dr.
Izdano: (2016)

Theory of electrostatics and electrokinetics of soft particles
od: Hiroyuki Ohshima
Izdano: (2009-01-01)

A quantitative methodology for the study of particle-electrode impacts
od: Little, C, i dr.
Izdano: (2018)

Mass transport limited currents at the tubular electrode
od: Thompson, M, i dr.
Izdano: (2005)

Single-entity electrochemistry: Diffusion-controlled transport of an analyte inside a particle
od: Le, H, i dr.
Izdano: (2018)

Numerical verification and experimental validation of the FEM model of collecting electrodes in a dry electrostatic precipitator
od: Andrzej Nowak

Anodic stripping voltammetry at a hydrodynamic mercury electrode under high mass transport conditions. 2. Experimental verification of theory and implications for sonovoltammetry
od: Agra-Gutierrez, C, i dr.
Izdano: (1998)

Voltammetry using multiple cycles: Porous electrodes
od: Chan, H, i dr.
Izdano: (2017)

Separation of Plastic Particles in Electrostatic Field Produced by Electrodes of Optimized Shape
od: Frantisek Mach, i dr.
Izdano: (2013-07-01)

Development of an Electrostatic Precipitator with Porous Carbon Electrodes to Collect Carbon Particles
od: Yoshihiro Kawada, i dr.
Izdano: (2019-07-01)

THE RELATIONSHIP BETWEEN MASS-TRANSPORT TO CHANNEL AND ROTATING-DISK ELECTRODES
od: Unwin, P, i dr.
Izdano: (1988)

Voltammetry at nanoparticle and microparticle modified electrodes: Theory and experiment
od: Streeter, I, i dr.
Izdano: (2007)

Testing and validating electroanalytical simulations.
od: Kätelhön, E, i dr.
Izdano: (2015)

Sweep voltammetry with a semi-circular potential waveform: electrode kinetics
od: Uchida, Y, i dr.
Izdano: (2019)

Linear sweep voltammetry with non-triangular waveforms at a microdisc electrode
od: Uchida, Y, i dr.
Izdano: (2018)

Voltammetry at electrodes decorated with an insulating porous film: Understanding the effects of adsorption
od: Chan, HTH, i dr.
Izdano: (2017)

Correction: Testing and validating electroanalytical simulations.
od: Kätelhön, F, i dr.
Izdano: (2016)

Correction: Testing and validating electroanalytical simulations.
od: Kätelhön, E, i dr.
Izdano: (2015)

THE RELATIONSHIP BETWEEN MASS-TRANSPORT TO CHANNEL AND ROTATING-DISK ELECTRODES - REPLY
od: Compton, R, i dr.
Izdano: (1988)

Characterising the nature of diffusion via a new indicator: Microcylinder and microring electrodes
od: Le, H, i dr.
Izdano: (2019)

Electrostatic field of cube electrodes
od: Veličković Dragutin M., i dr.
Izdano: (2004-01-01)

MASS-TRANSPORT TO CHANNEL AND TUBULAR ELECTRODES - THE SINGH AND DUTT APPROXIMATION
od: Compton, R, i dr.
Izdano: (1987)

Use of artificial intelligence in electrode reaction mechanism studies: Predicting voltammograms and analyzing the dissociative CE reaction at a hemispherical electrode
od: Chen, H, i dr.
Izdano: (2021)

Nanoparticles in sensing applications: on what timescale do analyte species adsorb on the particle surface?
od: Kätelhön, E, i dr.
Izdano: (2014)

Mechanism and Experimental Study on Electrostatic Atomization Using Needle-Shaped Electrodes
od: Hao Ma, i dr.
Izdano: (2023-05-01)

Diffusional transport to and through thin-layer nanoparticle film modified electrodes: capped CdSe nanoparticle modified electrodes.
od: Hepburn, W, i dr.
Izdano: (2014)

Hydrodynamics and mass transport in wall tube and microjet electrodes. Simulation and experiment for micrometer-scale electrodes
od: Melville, J, i dr.
Izdano: (2003)

Transient Voltammetry at Electrodes Modified with a Random Array of Spherical Nanoparticles: Theory
od: Belding, SR, i dr.
Izdano: (2010)

Adsorption processes coupled with mass transport at macro-electrodes: New insights from simulation
od: Yang, M, i dr.
Izdano: (2019)

Experimental Study on the Performance of a Novel Compact Electrostatic Coalescer with Helical Electrodes
od: Yi Shi, i dr.
Izdano: (2021-03-01)

Electrostatic Transport Characteristics of Olivine Particles under Electron Irradiation in Vacuum
od: Hong Gan, i dr.
Izdano: (2024-01-01)

Diffusional Cyclic Voltammetry at Electrodes Modified with Random Distributions of Electrocatalytic Nanoparticles: Theory
od: Belding, SR, i dr.
Izdano: (2009)

Sonovoltammetry at platinum electrodes: Surface phenomena and mass transport processes
od: Walton, D, i dr.
Izdano: (1995)

Non-linear sweep voltammetry of adsorbed species: theory and a method to determine formal potentials
od: Kätelhön, F, i dr.
Izdano: (2017)

Ohmic distortion of mass transport and of current-voltage curves at a channel electrode
od: Coles, B, i dr.
Izdano: (1996)

Electrodes modified with electroinactive layers: distinguishing through-film transport from pinhole (pore) diffusion.
od: Menshykau, D, i dr.
Izdano: (2009)