STEREOSELECTIVE REDUCTION OF (R,S)-[(ETA-5-C5H5)FE(CO)(PPH3)(=COCH2CH2CME2)]+ AND COMPLETE EPIMERIZATION OF THE KINETIC (RR,SS)-DIASTEREOISOMER TO THE THERMODYNAMIC (RS,SR)-DIASTEREOISOMER OF THE PRODUCT [(ETA-5-C5H5)FE(CO)(PPH3)(C(H)OCH2CH2CME2)]

Bibliographic Details
Main Authors:	Ayscough, A, Davies, S
Format:	Journal article
Published:	1986

ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS [FE(ETA-5-C5H5)(PHP(CH2CH2PPH2)2)]+, [FE(ETA-5-C5H5)(MEC(CH2PPH2)3)]+, AND [FE(ETA-5-C5H5)(C(CH2PPH2)4)]+
by: Davies, S, et al.
Published: (1983)

FRAGMENTATION OF (ETA-5-C5H5)FE(CO)(PPH3)(COCH2COR) COMPLEXES TO THE CATION [(ETA-5-C5H5)FE(CO)2(PPH3)]+
by: Davies, S, et al.
Published: (1983)

SELF-RECOGNITION BY THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] IN THE FORMATION OF (RR,SS)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2]2CH2
by: Bodwell, G, et al.
Published: (1991)

REGIOSELECTIVITY OF HYDRIDE ADDITION TO [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 AND REARRANGEMENT OF "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CO)H TO (ETA-4-C5H6)FE(PH2PCH2CH2PPH2)CO
by: Davies, S, et al.
Published: (1983)

CONFORMATION ANALYSIS OF COMPOUNDS OF THE TYPE [FE(ETA-5-C5H5)(CO)(PPH3)(CH2ALKYL)], "[FE(ETA-5-C5H5)(CO)(PPH3)(CH2ARYL)] - REPLY
by: Seeman, J, et al.
Published: (1985)

STEREOSPECIFICITY OF THE REARRANGEMENT OF THE ALPHA-ALKOXY IRON ACYL [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] TO THE ALPHA-METALLA-ESTER [(ETA-5-C5H5)FE(CO)(PPH3)CH2CO2CH2PH]
by: Davies, S, et al.
Published: (1987)

CHIRAL DISCRIMINATION IN THE REACTION OF THE ENOLATE [(ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]-LI+ WITH MONOSUBSTITUTED EPOXIDES - X-RAY CRYSTAL-STRUCTURE OF (RS,SR)-[(ETA-5-C5H5)FE(CO)(PPH3)(COCH2CH2CH(OH)ME)]
by: Brown, S, et al.
Published: (1985)

DISPROPORTIONATION OF THE IRON CARBONYL HYDRIDE "(ETA-5-C5H5)FE(CO)H(PH2PCH2CH2PPH2) TO THE IRON METHYL (ETA-5-C5H5)FE(PH2PCH2CH2PPH2)ME
by: Davies, S, et al.
Published: (1982)

HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
by: Davies, S, et al.
Published: (1983)

HYDRIDE REDUCTION OF THE CATION [ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
by: Davies, S, et al.
Published: (1982)

HYDRIDE REDUCTION OF THE CATIONS "((ETA-5-C5H5)FE[(PH2PCH2)3CME])PF6, ((ETA-5-C5H5)-RU[(PH2PCH2CH2)2PPH])PF6, AND ((ETA-5-C5H5)RU[PH2PCH2)3CME])PF6 - REGIOSELECTIVITY AND MECHANISM
by: Davies, S, et al.
Published: (1981)

CHIRAL DIENOLATES - STEREOSELECTIVE FORMATION AND ALPHA-ALKYLATION OF THE LITHIUM DIENOLATES DERIVED FROM (RS)-Z-[(ETA5-C5H5)FE(CO)(PPH3)COCH=CHCH2R] (R=ME,ET,N-PR) AND (RS)-[(ETA5-C5H5)FE(CO)(PPH3)(COCH=CME2)]
by: Davies, S, et al.
Published: (1986)

ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS ((ETA-5-C5H5)RU[MEC(CH2PPH2)3])+ AND "((ETA-5-C5H5)RU[PHP(CH2CH2PPH2)2])+
by: Davies, S, et al.
Published: (1983)

PREPARATION AND REACTIVITY OF THE ANION "[(ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]LI
by: Aktogu, N, et al.
Published: (1982)

CARBON-MONOXIDE REDUCTION - [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)H] - REACTIONS AND FORMATION BY REDUCTION OF THE COMPLEX [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)]PF6
by: Davies, S, et al.
Published: (1984)

STEREOCHEMICAL CONTROL AND MECHANISTIC ASPECTS OF THE ALKYLATION OF [(ETA-5-C5H5)FE(PPH3,PPH2NET2)(CO)(COCH(ME)ET)]-LI+ - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(PPH3)(CO)(COCH(ME)ET)]
by: Baird, G, et al.
Published: (1983)

DETERMINATION OF THE ABSOLUTE-CONFIGURATION AND OPTICAL PURITY OF [(ETA-5-C5H5)FE(CO)(PPH3)COME] - X-RAY CRYSTAL-STRUCTURE OF (R)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2CH2O[(R)-MENTHYL]]
by: Davies, S, et al.
Published: (1986)

EVIDENCE FOR THE IRON FORMYL "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CHO)
by: Davies, S, et al.
Published: (1982)

BIMETALLIC CYANO-BRIDGED CATIONS - PREPARATION AND HYDRIDE REDUCTION OF [(ETA-5-C5H5)L2RU(MU-CN)ML'2(ETA-5-C5H5)]PF6[L2,L'2=(PPH3)2,PH2PCH2CH2PPH2 - M = RU OR FE] - FORMATION OF [RU(ETA-5-C5H5)(PPH3)H3] AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)(PH2PCH2CH2PPH2)RU(MU-CN)RU(PPH3)2(ETA-5-C5H5)]PF6
by: Baird, G, et al.
Published: (1985)

ASYMMETRIC DIELS-ALDER REACTIONS - (S)-(+)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CH2] AS A CHIRAL ACRYLATE DIENOPHILE EQUIVALENT
by: Davies, S, et al.
Published: (1986)

ELABORATION OF ACYL LIGANDS - PREPARATION AND REACTIVITY OF THE ANION [ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]-
by: Aktogu, N, et al.
Published: (1984)

CONFORMATIONAL-ANALYSIS AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)(PPH3)CH2CH3]
by: Davies, S, et al.
Published: (1987)

CONFORMATIONAL-ANALYSIS FOR THE PSEUDO-OCTAHEDRAL COMPLEXES - [(ETA-5-C5H5)FE(CO)-(PPH3)CH2R
by: Blackburn, B, et al.
Published: (1987)

STEREOSELECTIVE ELABORATION OF THE ACYL LIGAND IN (ETA-5-C5H5)FE(CO)(PPH3)(COCH2R) VIA THE ALKYLATION OF THE ANIONS "[(ETA-5-C5H5)FE(CO)(PPH3)(COCHR)]LI (R = ME, ET)
by: Baird, G, et al.
Published: (1983)

STEREOSELECTIVE ADDITIONS TO THE ALKOXYCARBENE CATIONS [ETA-5-C5H5)FE(CO)(PPH3)(=CHOME)], [ETA-5-C5H5)FE(CO)(PPH3)(=CETOME)]
by: Baird, G, et al.
Published: (1984)

CONFORMATIONAL-ANALYSIS OF [(ETA-5-C5H5)FE(CO)(PPH3)CH2OME] - SOLVENT DEPENDENCE OF CONFORMER POPULATIONS
by: Blackburn, B, et al.
Published: (1987)

CONFORMATIONAL-ANALYSIS AND DYNAMICS OF THE TRIPHENYLPHOSPHINE LIGAND IN [(ETA-5-C5H5)FE(CO)(PPH3)COCH3]
by: Davies, S, et al.
Published: (1991)

REACTIVITY OF THE INORGANO-GRIGNARD "(ETA-5-C5H5)(PH2PCH2CH2PPH2)-FEMGBR TOWARDS HALOGENOGERMANES
by: Aktogu, N, et al.
Published: (1981)

CONFORMATIONAL-ANALYSIS AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)PPH3)CH2SIME3]
by: Davies, S, et al.
Published: (1987)

HYDRIDE ADDITION TO THE CATIONS [( ETA-5-C5H5)RU(L)2CO]+ (L=PPH3, L2=PH2PCH2CH2PPH2)
by: Davies, S, et al.
Published: (1984)

CHIRAL DIENOLATES - FORMATION AND STEREOSELECTIVE ALPHA-ALKYLATION OF THE LITHIUM DIENOLATE DERIVED FROM (Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-(Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME]
by: Davies, S, et al.
Published: (1987)

HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(TRIPHOS)]PF6 - DIRECT NUCLEOPHILIC-ATTACK ON THE METAL, AND HYDROGEN-EXCHANGE IN THE PRODUCT HYDRIDE (ETA-5-C5H5)FEH(TRIPHOS), (TRIPHOS=PH2PCH2CH2PPHCH2CH2PPH2)
by: Davies, S, et al.
Published: (1980)

CHIRAL ACETATE ENOLATE EQUIVALENT FOR THE SYNTHESIS OF BETA-HYDROXY ACIDS AND ESTERS - X-RAY CRYSTAL-STRUCTURE OF RR,SS-[ETA-5-C5H5)FE(CO)(PPH3)(COCH2CH(OH)CH2CH3)
by: Davies, S, et al.
Published: (1985)

A NOVEL ONE-POT SYNTHESIS OF HOMOCHIRAL (R)-(-) AND (S)-(+)-FE(CO)(ETA(5)-C5H5)(PPH(3))COCH3
by: Cook, S, et al.
Published: (1994)

CHEMISTRY OF (ETA-5-C5H5)RU(PH2PCH2CH2PPH2)CL - PREPARATION OF CATIONIC RUTHENIUM OLEFIN COMPLEXES
by: Davies, S, et al.
Published: (1980)

CHIRAL RECOGNITION IN THE REACTION OF THE ENOLATE DERIVED FROM [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] WITH 1-PHENYLETHYL BROMIDE
by: Davies, S, et al.
Published: (1990)

CHIRAL RECOGNITION IN THE SN2 REACTION OF TERT-BUTYL 2-BROMOPROPIONATE WITH THE ENOLATE DERIVED FROM [(ETA-5-C5H5)FE(CO)(PPH3)COCH3]
by: Collingwood, S, et al.
Published: (1990)

THE ASYMMETRIC-SYNTHESIS OF BETA-LACTAMS - STEREOCONTROLLED ASYMMETRIC TANDEM MICHAEL ADDITIONS AND SUBSEQUENT ALKYLATIONS OF E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH - CHME]
by: Davies, S, et al.
Published: (1986)

A NEW MECHANISM FOR EXCHANGE PROCESSES OBSERVED IN THE COMPOUNDS [NB(ETA-C5H5)2(EXO-ETA-RCH=CH2)H], [TA(ETA-C5H5)2(EXO-ETA-RCH=CH2)H]
by: Bercaw, J, et al.
Published: (1989)

CONFORMATION-REACTIVITY RELATIONSHIPS FOR THE ORGANOTRANSITION-METAL COMPLEXES (ETA-5-C5H5)FE(CO)(PPH3)R AND (ETA-5-C5H5)RE(NO)(PPH3)R (R = ALKYL AND ARYL)
by: Seeman, J, et al.
Published: (1985)

STEREOSELECTIVE REDUCTION OF (R,S)-[(ETA-5-C5H5)FE(CO)(PPH3)(=COCH2CH2CME2)]+ AND COMPLETE EPIMERIZATION OF THE KINETIC (RR,SS)-DIASTEREOISOMER TO THE THERMODYNAMIC (RS,SR)-DIASTEREOISOMER OF THE PRODUCT [(ETA-5-C5H5)FE(CO)(PPH3)(C(H)OCH2CH2CME2)]

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