Mixed sandwich carborane/thiamacrocycle compounds. Synthesis and characterization of 1-Ph-3,3,3-[9]aneS(3)-kappa(3)-S,S',S''-3,1,2-closo-RuC2B9H10 and 1,2-Ph(2)-3,3,3-[9]aneS(3)-kappa(3)-S,S',S''3,1,2-pseudocloso-RuC2B9H9
The reactions between [Ru([9]aneS3)(MeCN)3][CF3SO3] 2, a useful source of the [Ru{[9]aneS3-k3-S,S′,S″}]2+ fragment dication, and [Tl][TlC2B9H10Ph] and [Tl][TlC2B9H9Ph2], respectively sources of the {C2B9H10Ph}2- and {C2B9H9Ph2}2- fragment dianions, have afforded 1-Ph-3,3,3-[9]aneS3-k 3-S,S′,S″-3,1,2...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1996
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